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  • Chem Sci Trans., 2015, 4(2),  pp 620-628  

    DOI:10.7598/cst2015.1008

    Research Article

    Chemical Synthesis and Characterization of Poly(phenylhydrazine-co-4,4'-diaminodiphenyl Sulphone)

  • D. ILANGESWARAN* and G. LAKSHMI
  • Department of Chemistry, Rajah Serfoji Govt. College (Autonomous), Thanjavur -613005, India
  • Abstract

    A new copolymer with nanostructure was chemically synthesized using an oxidizing agent between phenyl hydrazine hydrochloride (PH.HCl) and biologically active 4,4'-diaminodiphenyl sulfone (DADPS). The copolymer showed considerable solubility in common organic solvents such as chloroform, dimethyl formamide (DMF), dimethyl sulphoxide (DMSO) and tetrahydrofuran (THF). The copolymer showed electrical conductivity of 2.14x10-2 S cm-1. The copolymer formation between these two monomers was confirmed by Fourier Transformation IR, 1H NMR spectral studies, X-ray diffraction studies and scanning electron microscopic (SEM) data. The UV-Visible spectrum also showed the presence of benzene and NH units in the copolymer.

    Keywords

    Copolymer, Phenyl hydrazine, FTIR, NMR, XRD, SEM

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