• image 01
    Volume 1, No.1, 2012
  • image 02
    Volume 1, No.2, 2012
  • image 01
    Volume 1, No.3, 2012
  • image 02
    Volume 2, No.1, 2013
  • image 02
    Volume 2, No.2, 2013
  • image 02
    Volume 2, No.S1, 2013
  • image 02
    Volume 2, No.3, 2013
  • image 02
    Volume 2, No.4, 2013
  • image 02
    Volume 3, No.1, 2014
  • image 02
    Volume 3, No.2, 2014
  • Volume 3, No3
    Volume 3, No.3, 2014
  • Volume 3, No4
    Volume 3, No.4, 2014
  • Volume 4, No1
    Volume 4, No.1, 2015
  • Volume 4, No2
    Volume 4, No.2, 2015
  • Volume 4, No3
    Volume 4, No.3, 2015
  • Volume 4, No4
    Volume 4, No.4, 2015
  • Volume 5, No1
    Volume 5, No.1, 2016
  • image 01
  • image 02
  • Login|Register
  • Chem Sci Trans., 2015, 4(2),  pp 629-637  

    DOI:10.7598/cst2015.1009

    Research Article

    2D Interwoven Metal-Organic Framework in Tetrachloromercurate(II) based Hybrid Material

  • MUKESH KUMAR1, SANJAY K. VERMA1, BIKRAM SINGH2, ATUL THAKUR2, AJIT KUMAR1 and DINESH JASROTIA1*
  • 1Department of Physics, Govt. G. M. Science College, Jammu (J & K)-180016, India
    2School of Physics & Materials Science, Shoolini University, Solan (H.P)-173212, India
  • Abstract

    The secondary interactions bonded crystal structure of p-phenylenediammonium tetrachloromercurate(II) has been studied by X-ray diffraction techniques and hyper-Raman Tensor studies. The tetrahedra hybrid structure exhibit two dimensional interwoven inorganic-organic layers mingle through N-H...Cl hydrogen bonding interactions. Organic layers are squash-in between Cl...Cl halogen bonded inorganic layers in p-phenylenediammonium tetrachloromercurate(II) with Cl...Cl distance = 3.628(3) Å and Hg-Cl...Cl=157.8(9)o. H2A atom is shared by two chlorine atoms [Cl1 and Cl3] and thus acts as bifurcated hydrogen atom with bifurcated hydrogen bond angle of 93.98(6) o. The antiparallel zig-zag bilayer inorganic-organic pattern present the p-phenylenediammonium tetrachloromercurate(II) into two-dimensional pattern along the ac-plane. The nearest centroid-centroid distance [3.86(4) Å] depicts that the contact is outlying to have any π... π interactions and the nearest hydrogen to centroid distance [2.82(3) Å] contributes to stability of crystal structure through C-H... π interactions. The initial Hyper-Raman tensors were calculated through polarization selection rules by using crystallographic Wyckoff positions.

    Keywords

    Hybrid materials, N-H...Cl hydrogen bonding, 2D Interwoven pattern

    This article has been viwed 1363 times

      

    Citations for this article 0

      

    No Citations