• image 01
    Volume 1, No.1, 2012
  • image 02
    Volume 1, No.2, 2012
  • image 01
    Volume 1, No.3, 2012
  • image 02
    Volume 2, No.1, 2013
  • image 02
    Volume 2, No.2, 2013
  • image 02
    Volume 2, No.S1, 2013
  • image 02
    Volume 2, No.3, 2013
  • image 02
    Volume 2, No.4, 2013
  • image 02
    Volume 3, No.1, 2014
  • image 02
    Volume 3, No.2, 2014
  • Volume 3, No3
    Volume 3, No.3, 2014
  • Volume 3, No4
    Volume 3, No.4, 2014
  • Volume 4, No1
    Volume 4, No.1, 2015
  • Volume 4, No2
    Volume 4, No.2, 2015
  • Volume 4, No3
    Volume 4, No.3, 2015
  • Volume 4, No4
    Volume 4, No.4, 2015
  • Volume 5, No1
    Volume 5, No.1, 2016
  • image 01
  • image 02
  • Login|Register
  • Chem Sci Trans., 2015, 4(4),  pp 1037-1042  

    DOI:10.7598/cst2015.1096

    Research Article

    DMF Solvated Structure of 3'-[(4-Fluorophenyl)- carbonyl]-5'-[2-(methylsulfanyl)ethyl]-4'-(phenyl)spiro[indole-3,2'-pyrrolidin]-2(1H)-one: A Pyrrolidine Alkaloidal Derivative

  • PREETIKA SHARMA1, M. SAPNAKUMARI2, B. NARAYANA2, B.K.SAROJINI3 and RAJNI KANT1*
  • 1X-ray Crystallography Laboratory, Department of Physics, University of Jammu, Jammu-Tawi-180006, India
    2Department of Studies in Chemistry, Mangalore University, Mangalagangotri-574199, India
    3 Department of Industrial Chemistry, Mangalore University, Mangalagangotri-574199, India
  • Abstract

    The compound 3'-[(4-fluorophenyl)carbonyl]-5'-[2-(methylsulfanyl)ethyl]4'-(phenyl) spiro[indole-3,2'-pyrrolidin]-2(1H)-one, C30H31FN3O3S, crystallizes in the orthorhombic space group P212121 with unit cell parameters, a = 6.3529(8) Å, b = 11.4335(14) Å, c = 38.405(4) Å, α = β = γ = 90.0o, Z=4. The crystal structure was solved by direct methods. The data were collected at room temperature (293 K) and the structure was refined by full-matrix least-squares procedures to a final R-value of 0.1015 for 3630 observed reflections. The molecular structure is stabilized by one intra [C-H?O] and one DMF-guided inter [N-H?O] molecular interaction. Besides this, few CH∙∙∙π interactions have also been observed

    Keywords

    Spiro-oxindole, Pyrrolidine, Direct method, Crystal structure, Intermolecular interactions

    This article has been viwed 1075 times

      

    Citations for this article 0

      

    No Citations