• image 01
    Volume 1, No.1, 2012
  • image 02
    Volume 1, No.2, 2012
  • image 01
    Volume 1, No.3, 2012
  • image 02
    Volume 2, No.1, 2013
  • image 02
    Volume 2, No.2, 2013
  • image 02
    Volume 2, No.S1, 2013
  • image 02
    Volume 2, No.3, 2013
  • image 02
    Volume 2, No.4, 2013
  • image 02
    Volume 3, No.1, 2014
  • image 02
    Volume 3, No.2, 2014
  • Volume 3, No3
    Volume 3, No.3, 2014
  • Volume 3, No4
    Volume 3, No.4, 2014
  • Volume 4, No1
    Volume 4, No.1, 2015
  • Volume 4, No2
    Volume 4, No.2, 2015
  • Volume 4, No3
    Volume 4, No.3, 2015
  • Volume 4, No4
    Volume 4, No.4, 2015
  • Volume 5, No1
    Volume 5, No.1, 2016
  • image 01
  • image 02
  • Login|Register
  • Chem Sci Trans., 2016, 5(1),  pp 187-196  

    DOI:10.7598/cst2016.1187

    Research Article

    Synthesis, Spectral Studies of Binuclear Divalent Metal Chelates Derived from Benzofuron-2-carbo-hydrazide and 1-Chloro-4-isothiocyanatobenzene

  • GAJENDRA KUMAR* and VIDHI SINGH
  • Chemical Science Laboratory, Bhagwant Institute of Technology, Muzaffarnagar-251315 (U.P), India
  • Abstract

    The M(II) complex of benzofuron-2-carbohydrazide, 1-chloro-4-isothiocyanatobenzene and nitrophenol (2-nitrophenol, 2,3- dinitropheno, 2,3,4- trinitrophenol) with transition metal ion e.g. Cu(II), Ni(II) and Co(II) were prepared. All the complex have structure formula [Cu2(C56H40N10Cl2O16S2)], [Ni2 (C56H40N10Cl2O16S2)], [Co2 (C56H40N10Cl2O16S2)], [Cu2 (C56H36N14 Cl2O24S2)], [Ni2 (C56H36N14Cl2O24S2)], [Co2 (C56H36N14Cl2O24S2)], [Cu2 (C56H32N18Cl2O32S2)], [Ni2 (C56H32N18Cl2O32S2)] and [Co2 (C56H32N18Cl2O32S2)] characterized by the several analytical techniques including elemental analysis (C.H.N.), molar conductance measurements, magnetic measurements, electronic, FAB mass, IR, 1H NMR and 13C NMR spectral studies. Based on these studies six coordinated octahedral geometry for all the complexes was proposed.

    Keywords

    Divalent metal complex, Benzofuron-2-carbohydrazide, 1-Chloro-4-isothiocyanatobenzene, Spectroscopic study

    This article has been viwed 1182 times

      

    Citations for this article 0

      

    No Citations