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  • Chem Sci Trans., 2018, 7(1),  pp 112-118  

    DOI:10.7598/cst2018.1434

    Research Article

    Synthesis and Crystal Structure of a Triply-Bridged Binuclear Cobalt(II) Dichloroacetate

  • M. GOGOI, S.J. BHARALI and B. K. DAS*
  • Department of Chemistry, Gauhati University, Guwahati-781014, Assam, India
  • Abstract

    A triply-bridged cobalt(II) tetracarboxylate complex, [Co2(η-OH2)(η-CHCl2COO)21-CHCl2COO)2(py)4] has been prepared and its crystal structure has been determined by single crystal x-ray diffraction to find that in this dinuclear cobalt(II) complex, the two metal centres are bridged by a water molecule and two dichloroacetato ligands. Each Co(II) centre is further coordinated to one monodentate dichloroacetato and two pyridine ligands. Supramolecular interactions stabilize the complex in the solid state.

    Keywords

    Cobalt(II) dichloroacetate, Aqua-bridged complex, Crystal structure

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