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  • Chem Sci Trans., 2018, 7(1),  pp 158-162  

    DOI:10.7598/cst2018.1461

    Research Article

    Crystal and Molecular Structure Study of the Complex Cd(L) 2Br2.C2H5OH (L=2-(4-Methylsulfanyl phenyl)-1H-benzimidazole)

  • M.N. MANJUNATHA1, MOHAMED ZIAULLA2* and M. CHANDRAKALA3
  • 1Department of Chemistry, M.S. Ramaiah Institute of Technology, M.S.R Nagar, Bangalore-560 054, Karnataka, India
    2Department of Chemistry, Impact College of Engineering and Applied Sciences, Bangalore-560 092, Karnataka, India
    3Department of Chemistry, Bangalore Institute of Technology, Bangalore-560 004, Karnataka, India
  • Abstract

    The complex, Cd(L)2Br2.C2H5OH, contains an ethanol molecule and dibromocadmate(II) coordinated to two benzimidazole moiety. In the crystal structure, the ethanol molecule is involved in four hydrogen bonds, viz. N-H...O, C-H...O, C-H...Br and O-H...Br intermolecular interactions network. Further the supramolecular assembly is stabilized by π-π stacking interactions between the benzimidazole and thiomethyl phenyl rings. Additionally, the metal ion, Cd(II) exhibits a distorted tetrahedral coordination of the bromine atoms.

    Keywords

    Benzimidazole derivative, Metal ligand complex, Crystal structure, Weak interactions

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