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  • Chem Sci Trans., 2018, 7(4),  pp 610-617  

    DOI:10.7598/cst2018.1496

    Research Article

    Synthesis and Characterization of Some Adducts of O-Hexyl Dithiocarbonates of Nickel(II) with Heterocyclic Amines

  • SHIVANGI SHARMA1, RENU SACHAR1, G.D. BAJJU1 and VIKAS SHARMA2
  • 1Department of Chemistry, University of Jammu, Baba Saheb Ambedkar Road, Jammu -180006, J & K, India
    2Division of Biochemistry, Faculty of Basic Sciences, SKUAST of Jammu, Main Campus Chatha, Jammu-180009, J & K, India
  • Abstract

    A series of adducts of o-hexyl dithiocarbonate of nickel(II) [(C6H13OCS2)2 Ni] have been synthesized in 1:2 molar ratio by the reaction of aqueous solution of NiCl2.6H2O with aqueous solution of potassium salt of o-hexyl dithiocarbonate. These complexes were further reacted with nitrogen donor ligands to obtain donor stabilized complex of the type [(C6H13OCS2)2 Ni.nL], (L=2-,3-,4-cyanopyridines and 2-,3-,4-aminopyridines, n=2). These adducts were characterized by elemental analysis, molar conductance, magnetic susceptibility measurements, IR and electronic spectral studies. The spectral studies revealed the trans octahedral geometry of the adducts around the Ni(II) metal ion. All the adducts were paramagnetic and non-electrolytic in nature. These complexes have also depicted the potential antifungal activity against the fungus Curvularia lunata.

    Keywords

    Nickel(II), O-hexyl dithiocarbonate, Curvularia lunata, Nitrogen donor ligands

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