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  • Chem Sci Trans., 2012, 1(2),  pp 257-260  

    DOI:10.7598/cst2012.150

    Research Article

    Coordination Aspects of Dimethyldithiocarbamate Ligand towards the First Series Transition Metal Ions

  • MOHAMMAD TARIQUE
  • Department of Chemistry, B.I.T.S. Masuri,Ghaziabad (U.P.)-201302, India
  • Abstract

    A series of chelates of first series transition metals with dimethyldithiocarbamate has been prepared. Physicochemical characterization of these chelates was done with the help of analytical data, molar conductance and FT-IR spectroscopy. All the colourless to colourful complexes were inert to atmospheric oxygen and moisture at room temperature. The analytical data indicated the composition ML2 for the chelates of Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) and MíL3 for those of Cr(III) and Fe(III). These complexes were observed to be non-ionic in nature. The FT-IR spectral data revealed the symmetrical coordination by the ligand.

    Keywords

    Dithiocarbamates, Transition metal chelates, Coordination aspects, Metal ions

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