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  • Chem Sci Trans., 2018, 7(3),  pp 477-487  

    DOI:10.7598/cst2018.1500

    Research Article

    Synthesis and Properties of Dinuclear Imine Complexes of Zn(II) and Cd(II) by Novel Route

  • VASISHTA D. BHATT1* and SAMAT R. RAM2
  • 1Department of Chemistry, School of Sciences,Gujarat University, Ahmedabad-380009, Gujarat, India
    2P.B. Science College, Kapadwanj- Gujarat, India
  • Abstract

    Mononuclear complexes of o-vanillin and 2-aminophenol with Zn(II) and Cd(II) were used as precursor to obtain new homo and heterodinuclear imine complexes. The complexes obtained by this new route using inter-complex reaction were then characterized by methods like elemental analysis, IR spectroscopy and thermogravimetric analysis. The powder x-ray diffractogram indicated crystalline nature with tetragonal symmetry of the complexes. The molecular ion peaks in the mass spectra supported the structures of dinuclear complexes. Finally, the structures of the complexes were confirmed using 1H and 13C NMR spectroscopy. A mechanism of the complex formation was proposed.

    Keywords

    Dinuclearcomplex, Inter-complex reaction, Schiff base

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