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  • Chem Sci Trans., 2019, 8(2),  pp 244-248  

    DOI:10.7598/cst2019.1580

    Research Article

    Synthesis and Crystal Structure Studies of Bis- [1-(p-methoxybenzyl)-2-(p-methoxyphenyl)-1H-benzimidazole]tetrabromidocadmate(II)

  • M. N. MANJUNATHA1, NOOR AFSHAN BANU2, MOHAMED ZIAULLA3*, FAZLUR REHMAN4 and PUTTA BORE GOWDA5
  • 1Department of Chemistry, M.S.Ramaiah Institute of Technology, M.S.R Nagar, Bangalore-560 054, Karnataka, India
    2Research Scholar, Department of Chemistry, Rayalaseema University, Kurnool, 518002, (AP), India
    3Department of Chemistry, Impact College of Engineering and Applied Sciences, Bangalore-560 092, Karnataka, India
    4Department of Chemistry, CMR Institute of Technology, Bangalore-560 037, Karnataka, India
    5Department of Mechanical Engineering, M.S Ramaiah Institute of Technology, M.S.R Nagar, Bangalore-560054, Karnataka, India
  • Abstract

    The complex Cd(L)2Br4, contains a dibromocadmate(II) coordinated to two benzimidazole moiety. In the crystal structure the molecules are further interconnected with weak intermolecular C-H???O hydrogen bonds generating a three-dimensional network. Further the supramolecular assembly is stabilized by Intermolecular C-H???π and π??? π interactions provide additional stability to the structure. Additionally the metal ion Cd(II) exhibits a distorted tetrahedral coordination of the bromine atoms.

    Keywords

    Benzimidazole derivative, Metal ligand complex, Crystal structure, C-H?O, Weak interactions

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