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  • Chem Sci Trans., 2019, 8(3),  pp 374-387  

    DOI:10.7598/cst2019.1592

    Research Article

    Structural Diversity in Organotin(IV) Carboxylates: A Study of X-Ray Crystallography

  • GARIMAMATELA1, ROBINAAMAN2* and NAGMANAZ2
  • 1Department of Chemistry, Kumaun University, GDC Jainti, Almora-263626, India
    2Department of Chemistry, Kumaun University, S.S.J.Campus Almora-263601, India
  • Abstract

    Among the organotin compounds, organotin(IV) carboxylates adapt a fascinating range of structural diversity, including monomer, dimer, tetramer, polymer, oligomer ladder, cyclic and hexameric drums structures. Generally four- and five coordinated complexes are observed in triorganotin(IV) complexes. While diorganotin(IV) complexes displayed a large range of structures, including five, six and seven coordinate geometries with distorted trigonalbipyramidal, octahedral and pentagonal bipyramidal structures. Distannoxanes complexes are also observed in diorganotin(IV) complexes. A comprehensive review, organotin(IV) carboxylates are presented with particular reference to their structural studies as described bycrystallography methods

    Keywords

    Organotin(IV) Carboxylate, Structural Chemistry, X-Ray crystallography

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