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  • Chem Sci Trans., 2013, 2(2),  pp 375-378  

    DOI:10.7598/cst2013.186

    Research Article

    Tributylphosphine as an Efficient Catalyst in C-Vinylation of Naphthol Derivatives

  • ALIREZA HASSANABADI, MOHAMMAD H. MOSSLEMIN and ZAHRA ALSADAT RASOLHOSSEINI
  • Department of Chemistry, Islamic Azad University, Zahedan Branch, P.O. Box 98135-978, Zahedan, Iran
    Department of Chemistry, Islamic Azad University, Yazd Branch, P.O. Box 89195-155, Yazd, Iran
  • Abstract

    A diastereospecific c-vinylation of naphthol derivatives is described from a reaction of dialkyl acetylenedicarboxylate and naphthol derivatives, in the presence of tributylphosphine as an efficient catalyst, in excellent yield. The presented one-pot method is simple and effective with mild conditions.

    Keywords

    C-Vinylation, Dialkyl acetylenedicarboxylates, Tributylphosphine, Naphthol derivatives

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