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  • Chem Sci Trans., 2013, 2(1),  pp 301-307  

    DOI:10.7598/cst2013.240

    Research Article

    Azo Group Containing Bis Ligand and its Coordination Polymers

  • HEMANG M. SHUKLA, YOGESH K. SOLANKI, ASHISH R. SHAH, DILIPSINH S. RAJ, AMISH I. SHAH and PURVESH J. SHAH
  • Chemistry Department, Shri A.N. Patel P.G. Institute, India
    Chemistry Department, M.B. Patel Science College, India
  • Abstract

    Novel bis ligand namely 2,2'-(4,4'-(4,4'-oxybis(4,1-phenylene) bis(diazene-2,1-diyl)) bis(4,1-phenylene))bis(azanediyl) bis (oxomethylene)dibenzoic acid (DDE) has been prepared and characterized. The coordination polymers based on this bis ligand with transition metal ions like Cu+2, Co+2, Ni+2, Mn+2 and Zn+2 were prepared and studied for their metal: ligand (M/L) ratio, IR and reflectance spectroscopies, magnetic properties, number average molecular weight and by thermogravimetry. All the novel synthesized compounds were screened for their antibacterial and antifungal activities.

    Keywords

    Coordination polymer, Bis azo ligand, Magnetic properties, Spectral studies and Microbicidal activity

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