• image 01
    Volume 1, No.1, 2012
  • image 02
    Volume 1, No.2, 2012
  • image 01
    Volume 1, No.3, 2012
  • image 02
    Volume 2, No.1, 2013
  • image 02
    Volume 2, No.2, 2013
  • image 02
    Volume 2, No.S1, 2013
  • image 02
    Volume 2, No.3, 2013
  • image 02
    Volume 2, No.4, 2013
  • image 02
    Volume 3, No.1, 2014
  • image 02
    Volume 3, No.2, 2014
  • Volume 3, No3
    Volume 3, No.3, 2014
  • Volume 3, No4
    Volume 3, No.4, 2014
  • Volume 4, No1
    Volume 4, No.1, 2015
  • Volume 4, No2
    Volume 4, No.2, 2015
  • Volume 4, No3
    Volume 4, No.3, 2015
  • Volume 4, No4
    Volume 4, No.4, 2015
  • Volume 5, No1
    Volume 5, No.1, 2016
  • image 01
  • image 02
  • Login|Register

  • HomeTable of ContentsList of ArticlesAbstract

    Chem Sci Trans., 2013, 2(1),  pp 222-226  

    DOI:10.7598/cst2013.290

    Research Article

    Electrochemical Reactions at Sacrificial Electrode: Direct Electrochemical Synthesis of Cadmium(II) Thiolates and their Coordination Compounds

  • BALJIT SINGH, KANCHAN BALA, GURPREET KAUR and SIMRAT SINGH
  • Department of Chemistry, Punjabi University, Patiala-147002, Punjab, India

    • Abstract

    The electrochemical synthesis of sulphur containing compounds derived from thiols (Ethanethiol, 2-propanethiol, 1-butanethiol, 2-methyl-2-propanethiol, 1-pentanethiol and thiophenol) at sacrificial cadmium anode and inert platinum cathode is reported. Adducts of these compounds with 1,10 phenanthroline and 2,2’-bipyridyl (L) have also been obtained by addition of these coligands to the electrolysis phase. These compounds have been characterized by microanalysis, physical measurements and IR spectral studies. General formula conforms to    Cd(SR)2 and Cd(SR)2.L. Current efficiencies of all these reactions are quite high.

    Keywords

    Electrochemical reactions, Sacrificial electrode, Cadmium(II) thiolates

    HISTORY

  • Received 4 July 2012
  • Accepted 28 July 2012

    • Author's Email

  • baljit_chemz@yahoo.co.in
  • Indexing Metadata
  • How to cite item
  • Review Policy
  • Rights & Permissions
  • Citation Alert
  • Order Reprints

    • This article has been viwed 5437 times

      

    Citations for this article 0

      

    No Citations