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  • Chem Sci Trans., 2013, 2(1),  pp 222-226  

    DOI:10.7598/cst2013.290

    Research Article

    Electrochemical Reactions at Sacrificial Electrode: Direct Electrochemical Synthesis of Cadmium(II) Thiolates and their Coordination Compounds

  • BALJIT SINGH, KANCHAN BALA, GURPREET KAUR and SIMRAT SINGH
  • Department of Chemistry, Punjabi University, Patiala-147002, Punjab, India
  • Abstract

    The electrochemical synthesis of sulphur containing compounds derived from thiols (Ethanethiol, 2-propanethiol, 1-butanethiol, 2-methyl-2-propanethiol, 1-pentanethiol and thiophenol) at sacrificial cadmium anode and inert platinum cathode is reported. Adducts of these compounds with 1,10 phenanthroline and 2,2-bipyridyl (L) have also been obtained by addition of these coligands to the electrolysis phase. These compounds have been characterized by microanalysis, physical measurements and IR spectral studies. General formula conforms to    Cd(SR)2 and Cd(SR)2.L. Current efficiencies of all these reactions are quite high.

    Keywords

    Electrochemical reactions, Sacrificial electrode, Cadmium(II) thiolates

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