• image 01
    Volume 1, No.1, 2012
  • image 02
    Volume 1, No.2, 2012
  • image 01
    Volume 1, No.3, 2012
  • image 02
    Volume 2, No.1, 2013
  • image 02
    Volume 2, No.2, 2013
  • image 02
    Volume 2, No.S1, 2013
  • image 02
    Volume 2, No.3, 2013
  • image 02
    Volume 2, No.4, 2013
  • image 02
    Volume 3, No.1, 2014
  • image 02
    Volume 3, No.2, 2014
  • Volume 3, No3
    Volume 3, No.3, 2014
  • Volume 3, No4
    Volume 3, No.4, 2014
  • Volume 4, No1
    Volume 4, No.1, 2015
  • Volume 4, No2
    Volume 4, No.2, 2015
  • Volume 4, No3
    Volume 4, No.3, 2015
  • Volume 4, No4
    Volume 4, No.4, 2015
  • Volume 5, No1
    Volume 5, No.1, 2016
  • image 01
  • image 02
  • Login|Register
  • Chem Sci Trans., 2013, 2(3),  pp 877-882  

    DOI:10.7598/cst2013.487

    Research Article

    Synthesis, Spectral Characterization and Biological Activities of Cr(III), Co(II), Ni(II) and Zn(II) Complexes with 4-Aminoantipyrine and Azide Ion as Ligands

  • K. RAJASEKAR*, T. RAMACHANDRAMOORTHY and S. BALASUBRAMANIYAN
  • Department of Chemistry, Government Arts College, Ariyalur- 621713, India
    PG and Research Department of Chemistry, Bishop Heber College (Autonomous), Tiruchirappalli- 620 017, India
  • Abstract

    The transition metal complexes of Cr(III), Co(II), Ni(II) and Zn(II) were synthesized with the ligands,
    4-aminoantipyrine (4-AAP) and azide ion. The structural aspects of the metal complexes were determined from elemental analysis, molar conductance measurements, IR, 1H NMR and 13C NMR spectral studies. Thermal stability of Co(II) complex was measured and the UV-Visible spectrum of Zn(II) complex also measured. Finally the antimicrobial and antifungal activities of the complexes were carried out by disc diffusion method. From the analytical and spectral data, the formulae of the complexes are arrived. The antimicrobial screening results indicate that the metal complexes are moderately active compared with those of pure ligand, 4-AAP.

    Keywords

    4-Aminoantipyrine, Azide, Complexes, Antifungal, Antimicrobial

    This article has been viwed 2138 times

      

    Citations for this article 1

      

    Download Citations