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  • Chem Sci Trans., 2014, 3(1),  pp 314-322  

    DOI:10.7598/cst2014.583

    Research Article

    Synthesis and Characterization of New Meso-Substituted and β-Substituted Unsymmetrical Metalloporphyrins

  • GAURI D BAJJU, NARINDER SINGH and DEEPMALA
  • Department of Chemistry University of Jammu, Jammu-18006, India
  • Abstract

    The synthesis and characterization of new meso-substituted and β-substituted unsymmetrical metallorphyrins has been described. A new modified Alder method was used for the synthesis of unsymmetrical porphyrins. Reaction of these unsymmetrical porphyrins with metal chlorides and nitrates afforded the corresponding metalloporphyrins in high yields with excellent purity. These porphyrins and their metal derivatives were characterized by spectroscopic methods.

    Keywords

    Meso-functionalization, Unsymmetrical metalloporphyrins, Metal ligand interaction

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