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  • Chem Sci Trans., 2013, 2(4),  pp 1358-1363  

    DOI:10.7598/cst2013.623

    Research Article

    Synthesis, Characterization, Antifungal and Insecticidal Studies of Some Thiocyanato-Bridged Bimetallic Complexes Containing Ni(II), Cd(II), Hg(II) & N, N'-Bis(benzylidene)
    1, 2-phenylenediamine Schiff Base

  • N. UPADHAYAY
  • Department of Chemistry, Pt. SNS Govt. PG College, Shahdol (M P), India
  • Abstract

    N,N-bis(benzylidene)-1,2-phenylenediamine Schiff base was prepared by the reaction of benzaldehyde with 1,2 phenylenediamine and its complexes of molecular formula [MM'(SCN)4 (BENDAMB)(1, 2)] (M = Ni2+; M = Cd2+, Hg2+) have been synthesized and characterized by elemental analyses, conductance measurement and various spectral studies. On the basis of softness parameter, spectral and magnetic studies monomeric bridged structure suggested for all the complexes. The antifungal activity against A.flaus, F.solani and Insecticidal screening against Red cotton bug (Dysdercus koenigii) of complexes has been done which shows good results.

    Keywords

    Bimetallic, Thiocyanato, Schiff base

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