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E-J Chem., 2010, 7(1),  pp 137- 142,    

Determination of Metastable Zone Width, Induction Period and Interfacial Energy of a Ferroelectric Crystal - Potassium Ferrocyanide Trihydrate (KFCT)

R. KANAGADURAI, R. DURAIRAJAN, R. SANKAR,
G. SIVANESAN, S. P. ELANGOVAN and R. JAYAVEL
Department of Physics, R.S. Govt. College, Thanjavur-613 005, India.
Department of Chemistry, R.S.Govt. College, Thanjavur-613 005, India.
Crystal Growth Centre, Anna University, Chennai-600 025, India.
J.J.College of Arts and Science, Pudukkottai-622 404, Tamil Nadu, India.
Received 7 July 2009  /   Accepted 27 August 2009

Abstract:  An order-disorder type potassium ferrocyanide trihydrate (KFCT) is a coordination compound forming lemon- yellow monoclinic ferroelectric crystals with curie temperature 251 K. KFCT crystals have been grown by temperature lowering solution growth technique. Solubility of KFCT has been determined for various temperatures. Metastable zone width, induction period and interfacial energy were determined for the aqueous solution of KFCT. Bulk crystal of potassium ferrocyanide trihydrate was grown with the optimized growth parameters. The grown crystal possesses good optical transmission in the entire UV-Visible region

Keywords: Crystal growth, Nucleation, Ferroelectric crystal, KFCT


 Corresponding author email id
srkanagadurai@yahoo.co.in

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