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  • Chem Sci Trans., 2014, 3(2),  pp 586-591  

    DOI:10.7598/cst2014.758

    Research Article

    Spectral and Thermal Studies of Some Binuclear Dimeric Mo-O-Mo Bridged Oxomolybdenum(V) Complexes with Bis(carboxamides) Derived from 4,4-Diaminobiphenyl, 1,4-diaminobenzene with Anhydrides

  • D. KANAGAVEL and M. MARIA ALBERT DENISON
  • Department of Chemistry, Kamaraj College, Tuticorin-628 003, Tamilnadu, India
  • Abstract

    A study of doubly bidentate ligands like 4,4-bis-(phthalamidyl)biphenyl Bd(PAH)2, 4,4-bis-(Succinamidyl)biphenyl Bd(SAH)2, 1,4-bis-(phthalamidyl)monophenyl PPD(PAH)2 and 1,4-bis-(succinamidyl)monophenyl PPD(SAH)2 with oxomolybdenum(V) is described. The complexes were prepared by reaction with the precursor (PyH)2[MoOCl5]. The coordination behavior of the complexes have been determined with the help of elemental composition, infrared and electronic spectroscopy, cyclicvoltammetric and thermal studies.

    Keywords

    Biscarboxyamides, 4,4-Diaminobiphenyl, 1,4- Diaminobenzene

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