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  • Chem Sci Trans., 2014, 3(4),  pp 1360-1365  

    DOI:10.7598/cst2014.880

    Research Article

    Synthesis and Characterization of Adducts of Bis(s-Alkyltrithiocarbonato)copper(II) with Oxygen Donor Ligands and Their Biological Activities

  • POOJA SHARMA, NEERUPAMA, GURPREET KOUR, RAJINDER SINGH and RENU SACHAR
  • Department of Chemistry, University of Jammu, Jammu, India
  • Abstract

    A new series of 1:2 adducts of bis(s-alkyl Trithiocarbonato)copper (where alkyl= ethyl, isopropyl and tertiarybutyl) have been prepared by reacting bis(s-alkyltrithiocarbonato)copper(II) with oxygen donor ligands. The resulting adducts have been characterized by elemental analysis, molar conductance, magnetic susceptibility measurement, biological studies, IR and UV-visible spectral studies. Analytical data reveals that Cu(II) complexes forms 1:2 adducts. Antifungal activity of some adducts have been carried out against the fungal strain Sclerotium rolfsii. Electronic and magnetic measurements indicate distorted octahedral geometry for the 1:2 adducts of Cu(II) adducts.

    Keywords

    S-Alkyltrithiocarbonato, Oxygen donor ligands, Sclerotium rolfsii

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