• image 01
    Volume 1, No.1, 2012
  • image 02
    Volume 1, No.2, 2012
  • image 01
    Volume 1, No.3, 2012
  • image 02
    Volume 2, No.1, 2013
  • image 02
    Volume 2, No.2, 2013
  • image 02
    Volume 2, No.S1, 2013
  • image 02
    Volume 2, No.3, 2013
  • image 02
    Volume 2, No.4, 2013
  • image 02
    Volume 3, No.1, 2014
  • image 02
    Volume 3, No.2, 2014
  • Volume 3, No3
    Volume 3, No.3, 2014
  • Volume 3, No4
    Volume 3, No.4, 2014
  • Volume 4, No1
    Volume 4, No.1, 2015
  • Volume 4, No2
    Volume 4, No.2, 2015
  • Volume 4, No3
    Volume 4, No.3, 2015
  • Volume 4, No4
    Volume 4, No.4, 2015
  • Volume 5, No1
    Volume 5, No.1, 2016
  • image 01
  • image 02
  • Login|Register
  • Chem Sci Trans., 2015, 4(1),  pp 251-257  

    DOI:10.7598/cst2015.942

    Research Article

    Preparation, Characterization and Biological Studies of Adducts of Bis(O-isopropyldithiocarbonato)oxovanadium(IV) with Nitrogen Donor Ligands

  • NEERUPAMA*, DEEPSHIKHA KHAJURIA, POOJA SHARMA and RENU SACHAR
  • Department of Chemistry, University of Jammu, Babasaheb Ambedkar Road, Jammu-180006, India
  • Abstract

    A series of adducts of bis(O-isopropyldithiocarbonato)oxovanadium(IV) with substituted pyridines have been synthesized by treating bis(O-isopropyldithiocarbonato)oxovanadium(IV) with substituted pyridines in acetone in equimolar ratios. Analytical results show that the adducts have 1:1 stoichiometry with general formula VO(O-isopropyldithiocarbonato)2L where L = 2 and 3-bromopyridine; 4-acetylpyridine; 3-hydroxypyridine; 2–methoxypyridine; 2-amino-3-methylpyridine; 2-amino-4-methylpyridine; 2-amino-6-methylpyridine). The addition complexes have been characterized by elemental analysis, conductivity measurements, magnetic susceptibility measurements, infrared and electronic spectral studies. These studies suggest a distorted octahedral structure and paramagnetic nature of the adducts. Antifungal activity of some adducts have been carried out against the fungal strain Sclerotium rolfsii.

    Keywords

    Oxovanadium(IV), O-isopropyldithiocarbonate, Sclerotium rolfsii

    This article has been viwed 1935 times

      

    Citations for this article 0

      

    No Citations