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  • Chem Sci Trans., 2015, 4(1),  pp 263-269  

    DOI:10.7598/cst2015.947

    Research Article

    Preparation and Characterization of the Adducts of Bis(morpholinedithiocarbamato)copper(II) with Nitrogen and Oxygen Donor Ligands

  • DEEPSHIKHA KHAJURIA*, POOJA SHARMA, NEERUPAMA and RENU SACHAR
  • Department of Chemistry, University of Jammu, Babasaheb Ambedkar Road, Jammu 180006, India
  • Abstract

    A series of new 1:1 and 1:2 adducts of Bis(morpholinedithiocarbamato)copper(II) with nitrogen and oxygen donors with general formula [Cu(morphdtc)2L] and [Cu(morphdtc)2L2] respectively (where L= 2-ethylpyridine, 2, 4, 6-collidine, dimethylsulphoxide and hexamethyl-phosphoramide) have been synthesized. The addition complexes have been characterized by elemental analysis, conductivity measurements, magnetic susceptibility measurements, TGA/DTA, infrared and electronic spectral studies. These studies suggest that 1:1 adducts are paramagnetic and may be assigned square pyramidal structure while 1:2 adducts are paramagnetic in nature and have a distorted octahedral structure. Antifungal activity of some adducts have been carried out against the fungal strain Sclerotium rolfsii.

    Keywords

    Morpholinedithiocarbamato, Ethylpyridine, Morpholine, Dimethylsulphoxide, Hexamethylphosphoramide, Sclerotium rolfsii

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