| DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
| 1 | Title | Title of Document | 2D Interwoven Metal-Organic Framework in Tetrachloromercurate(II) based Hybrid Material |
| 2 | Creator | Author's name, affiliation, country | MUKESH KUMAR1, SANJAY K. VERMA1, BIKRAM SINGH2, ATUL THAKUR2, AJIT KUMAR1 and DINESH JASROTIA1*
1Department of Physics, Govt. G. M. Science College, Jammu (J & K)-180016, India
2School of Physics & Materials Science, Shoolini University, Solan (H.P)-173212, India |
| 3 | Subject | Dicipline(s) | Chemical Science |
| 3 | Subject | Keywords | Hybrid materials, N-H...Cl hydrogen bonding, 2D Interwoven pattern |
| 4 | Description | Abstract | The secondary interactions bonded crystal structure of p-phenylenediammonium tetrachloromercurate(II) has been studied by X-ray diffraction techniques and hyper-Raman Tensor studies. The tetrahedra hybrid structure exhibit two dimensional interwoven inorganic-organic layers mingle through N-H...Cl hydrogen bonding interactions. Organic layers are squash-in between Cl...Cl halogen bonded inorganic layers in p-phenylenediammonium tetrachloromercurate(II) with Cl...Cl distance = 3.628(3) Å and Hg-Cl...Cl=157.8(9)o. H2A atom is shared by two chlorine atoms [Cl1 and Cl3] and thus acts as bifurcated hydrogen atom with bifurcated hydrogen bond angle of 93.98(6) o. The antiparallel zig-zag bilayer inorganic-organic pattern present the p-phenylenediammonium tetrachloromercurate(II) into two-dimensional pattern along the ac-plane. The nearest centroid-centroid distance [3.86(4) Å] depicts that the contact is outlying to have any π... π interactions and the nearest hydrogen to centroid distance [2.82(3) Å] contributes to stability of crystal structure through C-H... π interactions. The initial Hyper-Raman tensors were calculated through polarization selection rules by using crystallographic Wyckoff positions. |
| 5 | Publishers | Organizing agency, location | WWW Publications, India |
| 6 | Contributor | Sponsor(s) | - |
| 7 | Date | Date (YYYY-MM-DD) | - |
| 8 | Type | Status & genre | Peer-reviewed Article |
| 8 | Type | Type | |
| 9 | Formate | File Formate | PDF |
| 10 | Identifier | Uniform Resource Identifier | Click Here |
| 10 | Identifier | Digital Object Identifier | |
| 11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 4 , Number (2), (2015) |
| 12 | Lanuguage | English=en | en |
| 13 | Relation | Supp.files | |
| 14 | Coverage | | - |
| 15 | Copyright | Copyright and permissions | |
