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Studies on the Kinetics of Oxidation of 4-Oxo-4-phenylbutanoic Acid by Benzimidazolium Fluorochromate in the Presence of Oxalic Acid in Acetic Acid-Water Medium |
| DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
| 1 | Title | Title of Document | Studies on the Kinetics of Oxidation of 4-Oxo-4-phenylbutanoic Acid by Benzimidazolium Fluorochromate in the Presence of Oxalic Acid in Acetic Acid-Water Medium |
| 2 | Creator | Author's name, affiliation, country | I. VANNAMUTHU1,2, V. SALEEM MALIK1,
S. SYED SHAFI3 and S. SHEIK MANSOOR1*
1Department of Chemistry,
C. Abdul Hakeem College (Autonomous), Melvisharam - 632 509, Tamil Nadu, India
2Department of Chemistry,
Periyar Government Arts College, Cuddalore - 607001, Tamil Nadu, India
3Department of Chemistry,
Thiruvalluvar University, Serkadu, Vellore ? 632115, Tamil Nadu, India
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| 3 | Subject | Dicipline(s) | Chemical Science |
| 3 | Subject | Keywords | 4-Oxo acid, Kinetics, Oxidation, Benzimidazolium fluorochromate, Oxalic acid |
| 4 | Description | Abstract | Kinetics of oxidation of 4-oxo-4-phenyl butanoic acid (4-oxo acid) by benzimidazolium fluorochromate (BIFC) in acetic acid-water medium with perchloric acid in the presence of oxalic acid (OA) has been studied. The reaction is first order each in [BIFC], [4-oxo acid] and [H+]. The reaction has been found to be catalyzed by H+ ions. The reaction rate increased remarkably with the increase in the proportion of acetic acid in the solvent medium. Various thermodynamic parameters have been determined at different acetic acid-water composition. A suitable mechanism has been proposed. |
| 5 | Publishers | Organizing agency, location | WWW Publications, India |
| 6 | Contributor | Sponsor(s) | - |
| 7 | Date | Date (YYYY-MM-DD) | - |
| 8 | Type | Status & genre | Peer-reviewed Article |
| 8 | Type | Type | |
| 9 | Formate | File Formate | PDF |
| 10 | Identifier | Uniform Resource Identifier | Click Here |
| 10 | Identifier | Digital Object Identifier | |
| 11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 4 , Number (3), (2015) |
| 12 | Lanuguage | English=en | en |
| 13 | Relation | Supp.files | |
| 14 | Coverage | | - |
| 15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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