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Studies on the Kinetics of Oxidation of 4-Oxo-4-phenylbutanoic Acid by Benzimidazolium Fluorochromate in the Presence of Oxalic Acid in Acetic Acid-Water Medium

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1TitleTitle of DocumentStudies on the Kinetics of Oxidation of 4-Oxo-4-phenylbutanoic Acid by Benzimidazolium Fluorochromate in the Presence of Oxalic Acid in Acetic Acid-Water Medium
2CreatorAuthor's name, affiliation, country I. VANNAMUTHU1,2, V. SALEEM MALIK1, S. SYED SHAFI3 and S. SHEIK MANSOOR1*
1Department of Chemistry, C. Abdul Hakeem College (Autonomous), Melvisharam - 632 509, Tamil Nadu, India 2Department of Chemistry, Periyar Government Arts College, Cuddalore - 607001, Tamil Nadu, India 3Department of Chemistry, Thiruvalluvar University, Serkadu, Vellore ? 632115, Tamil Nadu, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords 4-Oxo acid, Kinetics, Oxidation, Benzimidazolium fluorochromate, Oxalic acid
4DescriptionAbstract Kinetics of oxidation of 4-oxo-4-phenyl butanoic acid (4-oxo acid) by benzimidazolium fluorochromate (BIFC) in acetic acid-water medium with perchloric acid in the presence of oxalic acid (OA) has been studied. The reaction is first order each in [BIFC], [4-oxo acid] and [H+]. The reaction has been found to be catalyzed by H+ ions. The reaction rate increased remarkably with the increase in the proportion of acetic acid in the solvent medium. Various thermodynamic parameters have been determined at different acetic acid-water composition. A suitable mechanism has been proposed.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier DOI:10.7598/cst2015.1036
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  4 , Number  (3), (2015)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
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