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Synthesis, Photophysical, Electrochemical and Thermal Studies of 2,3-Bithienylpyrazino[2,3-b]phenazine

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1TitleTitle of DocumentSynthesis, Photophysical, Electrochemical and Thermal Studies of 2,3-Bithienylpyrazino[2,3-b]phenazine
2CreatorAuthor's name, affiliation, country RAJESH M. KAMBLE*, AZAM M. SHAIKH and BHARAT K. SHARMA
Department of Chemistry, University of Mumbai, Santacruz (East), Mumbai-400 098, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Phenazine, BTTP, OLEDs
4DescriptionAbstract In this work, 2,3‒bithienylpyrazino[2,3‒b]phenazine [BTPP] was synthesized and its photophysical, electrochemical and thermal properties was studied and compared with 2,3‒bithienylquinoxaline [BTQ] and 2,3‒bithienylbenzo[g]quinoxaline [BTBQ]. The photophysical studies revealed that BTPP emit in the green region at λ max 551 nm. Electrochemical studies show that the ionization potential (HOMO) and electron affinity (LUMO) of BTPP are ‒5.49 eV and ‒3.15 eV respectively and are comparable to commonly used electron acceptor/transporter. The optical energy band gap of BTPP is 2.34 eV. Thermogravimetric analysis showed that BTPP possess good thermal stability.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier DOI:10.7598/cst2015.1050
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  4 , Number  (3), (2015)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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