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Kinetics of Oxidation of 3-Benzoylpropionic Acid by N-Bromobenzamide in Aqueous Acetic Acid Medium

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1TitleTitle of DocumentKinetics of Oxidation of 3-Benzoylpropionic Acid by N-Bromobenzamide in Aqueous Acetic Acid Medium
2CreatorAuthor's name, affiliation, country N. A. MOHAMED FAROOK* and A. AFROOS BANU
P. G & Research Department of Chemistry Khadir Mohideen College, Adirampattinam - 614 701, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Kinetics, Oxidation, N-Bromobenzamide, 4-Oxoacids, 3-Benzoylpropionic acid
4DescriptionAbstract The kinetics of the oxidation of 3-benzoylpropionic acid (KA) by N-bromobenzamide (NBA) to yield the corresponding carboxylic acid were studied potentiometrically in 50:50 (v/v) aqueous acetic acid medium at 298 K. The effects of temperature, composition of solvent medium and concentration of added mineral acid on the rate of reaction were also studied. The reaction was first order with respect to the [KA], [NBA] and hydrogen ions. There is no effect of added benzamide. Protonated NBA has been postulated as the reactive oxidizing species.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  4 , Number  (2), (2015)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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