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Micellar Catalysed Kinetic Oxidation Study of Acetophenone by N-Bromosaccharin in Aqueous Acetic Acid Medium

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1TitleTitle of DocumentMicellar Catalysed Kinetic Oxidation Study of Acetophenone by N-Bromosaccharin in Aqueous Acetic Acid Medium
2CreatorAuthor's name, affiliation, country V. K. SHARMA, ILA JAIN*, PREETI SINGH and K. SHARMA
Department of Chemistry, Govt. Motilal Vigyan Mahavidyalaya, Bhopal, M.P. India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Kinetics, Oxidation, Acetophenone, N-Bromosaccharin, Micelles
4DescriptionAbstract The kinetic oxidation study of acetophenone by N-bromosaccharin in aqueous acetic acid medium and in presence of Hg(II) acetate was investigated in the presence of both cationic and anionic micelles. The reaction obeys first order kinetics in oxidant both in the presence as well as absence of micelle. The kinetic results for dependence on substrate concentration indicate intermediate complex formation between oxidant and substrate species. The reactions are acid catalysed and follow both acid dependent and independent path. Change in polarity of the medium, effect of addition of saccharin and Hg(II) acetate have also been investigated. Both type of micelles catalyses the oxidation. Binding parameters have been calculated by analyzing the data using the model suggested by Piszkiewicz. On the basis of kinetic results probable mechanism is proposed
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  4 , Number  (4), (2015)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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