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Synthesis of Derivatives of Organoheterotrimetallic dibutyl-[Al(III), Sn(IV), Ti(IV)]- μ -oxoisopropoxide- μ-oxo n-Propoxide with Salicylates |
| DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
| 1 | Title | Title of Document | Synthesis of Derivatives of Organoheterotrimetallic dibutyl-[Al(III), Sn(IV), Ti(IV)]- μ -oxoisopropoxide- μ-oxo n-Propoxide with Salicylates |
| 2 | Creator | Author's name, affiliation, country | AMARDEEP*, PANKAJ BHATIA, BRIJ MOHAN and H. K. SHARMA
Department of Chemistry, Kurukshetra University, Kurukshetra-136119, India |
| 3 | Subject | Dicipline(s) | Chemical Science |
| 3 | Subject | Keywords | Tin diacetate, Aluminium isopropoxide, Titanium, Methyl salicylate, Chloromethyl salicylate |
| 4 | Description | Abstract | Tin diacetate and aluminium isopropoxide in equimolar proportion in xylene affords the complex [(OAc)SnOAl(OPri)2] which on reaction with Ti(OPrn)4 in 1:1 molar ratio yielded a new organoheterotrimetallic-μ-oxoisopropoxide-μ-oxo-n-propoxide [SnO2TiAl(OPri)2(OPrn)3] with continuous liberation of isopropyl acetate and propyl acetate formed during the course of reaction. The preparation of some important salicylates (methyl salicylate, chloro methyl salicylate, phenyl salicylate, phenyl 2-hydroxy 5-chloro benzoate) derivatives of compound [Bu2SnO2TiAl (OPri)2(OPrn)3] have been carried out in different molar ratios(1:1 and 1:2) in refluxing benzene. The complexes were further characterized by spectral analysis (IR, 1H, 13C, 119Sn, 27Al NMR and mass spectra).The spectral studies confirmed the proposed framework of the new organoheterotrimettalic complexes and indicated a tetrahedral geometry around the central metal atom |
| 5 | Publishers | Organizing agency, location | WWW Publications, India |
| 6 | Contributor | Sponsor(s) | - |
| 7 | Date | Date (YYYY-MM-DD) | - |
| 8 | Type | Status & genre | Peer-reviewed Article |
| 8 | Type | Type | |
| 9 | Formate | File Formate | PDF |
| 10 | Identifier | Uniform Resource Identifier | Click Here |
| 10 | Identifier | Digital Object Identifier | |
| 11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 4 , Number (4), (2015) |
| 12 | Lanuguage | English=en | en |
| 13 | Relation | Supp.files | |
| 14 | Coverage | | - |
| 15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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