Indexing Metadata
Highly Efficient and Greener Approach for Fluorinating Organic Compounds |
| DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
| 1 | Title | Title of Document | Highly Efficient and Greener Approach for Fluorinating Organic Compounds |
| 2 | Creator | Author's name, affiliation, country | SURENDER KUMAR DHINGRA1*, PURNIMA NAG2 and RAHUL SAXENA1
1Research and Development Centre, SRF Limited, Bhiwadi, Rajasthan-301019, India
2Department of Chemistry, Jaipur National University, Jaipur, Rajasthan-302017, India |
| 3 | Subject | Dicipline(s) | Chemical Science |
| 3 | Subject | Keywords | Ionic liquids, Halex, Green chemistry, Fluorinated organic compounds |
| 4 | Description | Abstract | The introduction of fluoride by nucleophilic aromatic substitution is found to be more effective when ionic liquids e.g. 1-butyl-3-methylimidazolium tetrafluoroborate and 1-butyl-3-methylimidazolium hexafluorophosphate are used as a solvent. The use of the ionic liquids increased the yield and lowered the reaction temperature of similar fluorination reactions vis-?-vis organic solvents. In absence of any suitable solvent for fluorination reactions, the ionic liquids appear to be most suitable option especially for large scale. We propose a simple, efficient and green reaction protocol for the preparation of fluorinated organic compounds by sequential halogen exchange of aromatic in the presence of ionic liquids. The operational simplicity, low temperature, high yield, eco-friendly, safe, easily scalable processes with recyclability of ionic liquids are major benefits |
| 5 | Publishers | Organizing agency, location | WWW Publications, India |
| 6 | Contributor | Sponsor(s) | - |
| 7 | Date | Date (YYYY-MM-DD) | - |
| 8 | Type | Status & genre | Peer-reviewed Article |
| 8 | Type | Type | |
| 9 | Formate | File Formate | PDF |
| 10 | Identifier | Uniform Resource Identifier | Click Here |
| 10 | Identifier | Digital Object Identifier | |
| 11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 4 , Number (4), (2015) |
| 12 | Lanuguage | English=en | en |
| 13 | Relation | Supp.files | |
| 14 | Coverage | | - |
| 15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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