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Synthesis and Structural Characterization Studies on Solid Polymer Electrolyte System with Magnesium Triflate as Host Salt, EC as Plasticizer and MgO as Nanofiller

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1TitleTitle of DocumentSynthesis and Structural Characterization Studies on Solid Polymer Electrolyte System with Magnesium Triflate as Host Salt, EC as Plasticizer and MgO as Nanofiller
2CreatorAuthor's name, affiliation, country S. SAROJINI* and C. ANJALAI
PG and Research Department of Physics, Queen Mary?s College (A), Chennai- 600004, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Solution-casting method, Solid polymer electrolytes, Differential scanning calorimetry, Fourier transform infrared spectroscopy
4DescriptionAbstract The present investigation describes the preparation, structural characterization studies on three different systems namely; system-I ((PMMA + PVDF)v- (Mg(CF3SO3)2)1-y), where 1-y = 60, 50, 40, 30 and 20 mol% respectively, System - II ((PMMA + PVDF) y - (Mg(CF3SO3)2)1-y) z-(EC) 1-z, where 1-z = 25, 20, 15, 10 and 5 mol% respectively and System-III (((PMMA + PVDF) v - (Mg(CF3SO3)2)1-y) z - (EC) 1-z) b - (MgO) 1-b,where 1-b = 20, 15, 10 and 5 mol% respectively and these systems were prepared by solution-casting technique. In system-III the MgO nanofiller of 32 nm size prepared by wet chemical sol-gel method is added to arrive at nanocomposite solid polymer electrolyte systems in four different compositions namely 1-b = 20, 15, 10 and 5 mol% respectively. The synthesized MgO nanofiller size was confirmed by TEM study. Experimental techniques such as x-ray diffraction analysis, Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC) and surface morphological studies involving optical microscopy have been employed to explore their structural properties.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  5 , Number  (3), (2016)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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