Indexing Metadata
Kinetics and Mechanism of Oxidation of Malic Acid by Morpholinium Fluorochromate in Aqueous Acetonitrile Medium |
| DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
| 1 | Title | Title of Document | Kinetics and Mechanism of Oxidation of Malic Acid by Morpholinium Fluorochromate in Aqueous Acetonitrile Medium |
| 2 | Creator | Author's name, affiliation, country | N.M.I. ALHAJI,1* R. MAMANI2 and K. KAYALVIZHI1
1P.G. & Research Department of Chemistry, Khadir Mohideen College, Adirampattinam, Tamilnadu-614701, India
2Department of Chemistry, Bon Secours College, Thanjavur, Tamilnadu, India
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| 3 | Subject | Dicipline(s) | Chemical Science |
| 3 | Subject | Keywords | Oxidation, Kinetics, Mechanism, Malic acid, Morpholinium fluorochromate |
| 4 | Description | Abstract | Kinetics of oxidation of malic acid by morpholinium fluorochromate (MFC) in 50% (v/v) acetonitrile-water solvent mixture at 298 K in the presence of perchloric acid has been studied spectrophotometrically. The reaction is first order each with respect to malic acid, MFC and H+ ion. Variation of ionic strength of the reaction medium or addition of acrylonitrile does not influence the reaction. However, the rate of reaction decreases significantly on addition of manganese sulphate. The reaction is favoured by lowering of solvent polarity. Activation parameters, Ea, ΔH‡, ΔS‡ and ΔG‡ have been evaluated from the rate constant values measured at four different temperatures using Arrhenius and Eyring equations. Based on these findings, a suitable mechanism has been proposed |
| 5 | Publishers | Organizing agency, location | WWW Publications, India |
| 6 | Contributor | Sponsor(s) | - |
| 7 | Date | Date (YYYY-MM-DD) | - |
| 8 | Type | Status & genre | Peer-reviewed Article |
| 8 | Type | Type | |
| 9 | Formate | File Formate | PDF |
| 10 | Identifier | Uniform Resource Identifier | Click Here |
| 10 | Identifier | Digital Object Identifier | |
| 11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 5 , Number (1), (2016) |
| 12 | Lanuguage | English=en | en |
| 13 | Relation | Supp.files | |
| 14 | Coverage | | - |
| 15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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