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A Powerful Organocatalytic Methodology for the Synthesis of Spiro-Epoxyoxindoles from Ylideneoxindoles Using tert-Butyl Hydroperoxide

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1TitleTitle of DocumentA Powerful Organocatalytic Methodology for the Synthesis of Spiro-Epoxyoxindoles from Ylideneoxindoles Using tert-Butyl Hydroperoxide
2CreatorAuthor's name, affiliation, country MUKESH KUMAR TYAGI* and SANTOSH KUMAR SRIVASTAVA
Department of Chemistry, Dr. H. S. Gour University (A Central University) Sagar-470003(M.P.), India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Ylideneoxindoles, Bifunctional organocatalyst, TBHP, DFT
4DescriptionAbstract Noncovalent organocatalysed epoxidation of ylideneoxindoles is experimentally, theortically and technologically importance. Stereoselective epoxidation for ylideneoxindole cyclohexane-1,3-diones have been successfully designed. Spiro compounds have been formed with two adjacent new stereocentres. The transition state created by H-bonding between bifunctional catalyst and substrate. This procedure is permit to synthesize wide variety of functional groups and gives excellent yields. Furthermore, the bifunctional catalyst could be reused and recovered.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier DOI:10.7598/cst2017.1205
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  6 , Number  (3), (2017)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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