Indexing Metadata
A New Bulk and Nanostructure Supramolecular Compound [Co(dipic)2MnO2]n, Synthesis and
Crystal Structure
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| DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
| 1 | Title | Title of Document | A New Bulk and Nanostructure Supramolecular Compound [Co(dipic)2MnO2]n, Synthesis and
Crystal Structure
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| 2 | Creator | Author's name, affiliation, country | Z. RAZMARA, A .R. REZVANI* and H. SARAVANI
Department of Chemistry, University of Sistan and Baluchestan,
P.O.Box 98135-674, Zahedan, Iran
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| 3 | Subject | Dicipline(s) | Chemical Science |
| 3 | Subject | Keywords | Sonochemical method, Nano-sized polymer, Crystal structure, Bulk polymer, Binuclear complex |
| 4 | Description | Abstract | The nano and bulk structure polymer [Co(dipic)2Mn(O)2]n (where dipic is pyridine-2,6-dicarboxylic acid), was synthesized by sonochemical method and reflux process respectively. The bulk structure was characterized using single-crystal x-ray diffraction (SC-XRD). The crystal structure of this polymer, which was synthesized using a reflux approach, was found to be a binuclear coordination polymer. In this structure, the cobalt center achieves hexa-coordination by coordinating with two deprotonated dipicolinate groups, acting as tridentate chelating ligands. Manganese center achieves tetra-coordination with four µ-carboxylate oxygen from the dipic ligand of Co(dipic) 2-2. The nanostructure of this polymer was characterized using scanning electron microscopy (SEM), x-ray powder diffraction (XRD) and FT-IR spectroscopy and compared with bulk structure polymer. |
| 5 | Publishers | Organizing agency, location | WWW Publications, India |
| 6 | Contributor | Sponsor(s) | - |
| 7 | Date | Date (YYYY-MM-DD) | - |
| 8 | Type | Status & genre | Peer-reviewed Article |
| 8 | Type | Type | |
| 9 | Formate | File Formate | PDF |
| 10 | Identifier | Uniform Resource Identifier | Click Here |
| 10 | Identifier | Digital Object Identifier | |
| 11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 5 , Number (2), (2016) |
| 12 | Lanuguage | English=en | en |
| 13 | Relation | Supp.files | |
| 14 | Coverage | | - |
| 15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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