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A New Bulk and Nanostructure Supramolecular Compound [Co(dipic)2MnO2]n, Synthesis and Crystal Structure

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1TitleTitle of DocumentA New Bulk and Nanostructure Supramolecular Compound [Co(dipic)2MnO2]n, Synthesis and Crystal Structure
2CreatorAuthor's name, affiliation, country Z. RAZMARA, A .R. REZVANI* and H. SARAVANI
Department of Chemistry, University of Sistan and Baluchestan, P.O.Box 98135-674, Zahedan, Iran
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Sonochemical method, Nano-sized polymer, Crystal structure, Bulk polymer, Binuclear complex
4DescriptionAbstract The nano and bulk structure polymer [Co(dipic)2Mn(O)2]n (where dipic is pyridine-2,6-dicarboxylic acid), was synthesized by sonochemical method and reflux process respectively. The bulk structure was characterized using single-crystal x-ray diffraction (SC-XRD). The crystal structure of this polymer, which was synthesized using a reflux approach, was found to be a binuclear coordination polymer. In this structure, the cobalt center achieves hexa-coordination by coordinating with two deprotonated dipicolinate groups, acting as tridentate chelating ligands. Manganese center achieves tetra-coordination with four -carboxylate oxygen from the dipic ligand of Co(dipic) 2-2. The nanostructure of this polymer was characterized using scanning electron microscopy (SEM), x-ray powder diffraction (XRD) and FT-IR spectroscopy and compared with bulk structure polymer.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier DOI:10.7598/cst2016.1211
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  5 , Number  (2), (2016)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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