Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
Home | Table of Contents | Submit an article | Subscribe | Login | Register

Indexing Metadata

Kinetics of Oxidation of 3-Benzoylpropionic Acid by N-Chloroacetamide in Aqueous Acetic Acid Medium

DUBLINCOREMETADATA ITEM METADATA FOR THIS DOCUMENT
1TitleTitle of DocumentKinetics of Oxidation of 3-Benzoylpropionic Acid by N-Chloroacetamide in Aqueous Acetic Acid Medium
2CreatorAuthor's name, affiliation, country N. A. MOHAMED FAROOK* and S. MANOCHITRA
P. G & Research Department of Chemistry Khadir Mohideen College, Adirampattinam - 614 701, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Kinetics, Oxidation, N-Chloroacetamide, 4-Oxoacids, 3-Benzoylpropionic acid
4DescriptionAbstract Kinetics of the oxidation of 3-benzoylpropionic acid (KA) by N-chloroacetamide (NCA)in aqueous acetic acid medium has been studied. The reaction followed potentiometrically at 298K. The effects of temperature, composition of solvent medium and concentration of added mineral acid on the rate of reaction were also studied. The reaction exhibits first order each [KA], [NCA] and hydrogen ions. Variation in ionic strength has no effect on the reaction rate, while the reaction rates are enhanced on lowering the dielectric constant of the reaction medium. There is no effect of added acetamide. Protonated NBB has been postulated as the reactive oxidizing species. The mechanism proposed involves the attack of the H2O+Cl on the enol form of the 4-oxo acid
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier DOI:10.7598/cst2016.1244
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  5 , Number  (2), (2016)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
Home | Table of Contents | Submit an article | Subscribe | Login | Register