DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
1 | Title | Title of Document | Kinetics of Oxidation of 3-Benzoylpropionic Acid by
N-Chloroacetamide in Aqueous Acetic Acid Medium
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2 | Creator | Author's name, affiliation, country | N. A. MOHAMED FAROOK* and S. MANOCHITRA P. G & Research Department of Chemistry
Khadir Mohideen College, Adirampattinam - 614 701, India
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3 | Subject | Dicipline(s) | Chemical Science |
3 | Subject | Keywords | Kinetics, Oxidation, N-Chloroacetamide, 4-Oxoacids, 3-Benzoylpropionic acid |
4 | Description | Abstract | Kinetics of the oxidation of 3-benzoylpropionic acid (KA) by N-chloroacetamide (NCA)in aqueous acetic acid medium has been studied. The reaction followed potentiometrically at 298K. The effects of temperature, composition of solvent medium and concentration of added mineral acid on the rate of reaction were also studied. The reaction exhibits first order each [KA], [NCA] and hydrogen ions. Variation in ionic strength has no effect on the reaction rate, while the reaction rates are enhanced on lowering the dielectric constant of the reaction medium. There is no effect of added acetamide. Protonated NBB has been postulated as the reactive oxidizing species. The mechanism proposed involves the attack of the H2O+Cl on the enol form of the 4-oxo acid |
5 | Publishers | Organizing agency, location | WWW Publications, India |
6 | Contributor | Sponsor(s) | - |
7 | Date | Date (YYYY-MM-DD) | - |
8 | Type | Status & genre | Peer-reviewed Article |
8 | Type | Type | |
9 | Formate | File Formate | PDF |
10 | Identifier | Uniform Resource Identifier | Click Here |
10 | Identifier | Digital Object Identifier | |
11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 5 , Number (2), (2016) |
12 | Lanuguage | English=en | en |
13 | Relation | Supp.files | |
14 | Coverage | | - |
15 | Copyright | Copyright and permissions | |