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AC Impedance Analysis of PVP:(H2N-C6H4-SO3H) Complexed Polymer Electrolyte Films

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1TitleTitle of DocumentAC Impedance Analysis of PVP:(H2N-C6H4-SO3H) Complexed Polymer Electrolyte Films
2CreatorAuthor's name, affiliation, country R. S. DIANA SANGEETHA*, P. THILLAI ARASU, G. HIRAN KUMAR and R. S. DARIES BELLA
Department of Chemistry, Vickram College of Engineering, Sivagangai-630 561, India
Department of Chemistry, Manonmaniam Sundaranar University, Tirunelveli, India
Department of Chemistry, PSN Engineering College, Tirunelveli-627 152, India
Centre for Scientific and Applied Research, PSN College of Engineering and Technology, Tirunelveli-627152, India
Physics Research Centre, Department of Physics, St. Xavier's College, Palayamkottai, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Polyvinyl pyrrolidone, 2, 3, 4-Amino benzene sulphonic acid, Impedance spectroscopy, Polymer electrolyte
4DescriptionAbstract A solid polymer electrolyte system based on polyvinyl pyrrolidone (PVP) complexed with amino benzene sulphonic acid isomers have been prepared by solution casting technique. The conductivity measurements were carried out on these films as a function of frequency at various temperatures. The complex impedance spectroscopy results reveal that the high-frequency depressed semicircle is due to the bulk effect of the material. The conductivity is enhanced to the order of 10-6 S/cm upon increase in salt concentration at room temperature. The 2 and 4-amino benzene sulphonic acid enhances the conductivity of PVP by donating its proton from the sulphonic acid group very effectively. Thus the maximum ionic conductivity (8.44x 10-6 S/cm) is obtained for 9 mol% 2-amino benzene sulphonic acid (2ABSA) complexed PVP polymer electrolyte.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier DOI:10.7598/cst2016.1272
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  5 , Number  (3), (2016)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
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