Indexing Metadata
Synthesis and Photophysical Properties of 5-Methoxy-naphtho[1,2-d]thiazole-2-carboxylic Acid |
| DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
| 1 | Title | Title of Document | Synthesis and Photophysical Properties of 5-Methoxy-naphtho[1,2-d]thiazole-2-carboxylic Acid |
| 2 | Creator | Author's name, affiliation, country | J. RAMCHANDER
Department of Chemistry, Nizam College, Osmania University, Hyderabad,
Telangana State-500001, India
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| 3 | Subject | Dicipline(s) | Chemical Science |
| 3 | Subject | Keywords | 4-Methoxynaphthyl amine, Naphthothiazole, Solvatochromism, Stokes shift, Fluorophore |
| 4 | Description | Abstract | Synthesis of 5-methoxynaphtho[1, 2-d]thiazole-2-carboxylic acid was developed from new synthetic route starting from using potassium ferricyanide as catalyst. The absorption and fluorescence properties of structurally related 4-methoxynaphthalene-1-ylamine (4), N-(4-methoxynaphthalene-1-yl)-oxalamic acid ethyl ester (5), 2-(4-methoxynaphthalene-1-ylamino)-2-thioxoacetic acid (6) and 5-methoxynaphtho[1,2-d]thiazole-2-carboxylic acid (7) were investigated in 4 different solvents. The absorption maxima of these compounds (except 7) in the order C6H6 > cyclohexane >MeOH>EtOH+HCl. The spectral characteristics are solvent and compound specific. Fluorophores with electron withdrawing group have larger fluorescence quantum yields and greater solvatochromism than the compounds with electron donating groups. Protic solvents yielded higher fluorescence quantum efficiency. While no such relationship exists between the latter and electronic absorption maxima, fluorescence emission maxima, fluorescence quantum efficiency and Stokes shift. |
| 5 | Publishers | Organizing agency, location | WWW Publications, India |
| 6 | Contributor | Sponsor(s) | - |
| 7 | Date | Date (YYYY-MM-DD) | - |
| 8 | Type | Status & genre | Peer-reviewed Article |
| 8 | Type | Type | |
| 9 | Formate | File Formate | PDF |
| 10 | Identifier | Uniform Resource Identifier | Click Here |
| 10 | Identifier | Digital Object Identifier | |
| 11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 6 , Number (1), (2017) |
| 12 | Lanuguage | English=en | en |
| 13 | Relation | Supp.files | |
| 14 | Coverage | | - |
| 15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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