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FT-IR Studies of Nickel Substituted Polycrystalline Zinc Spinel Ferrites for Structural and Vibrational Investigations

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1TitleTitle of DocumentFT-IR Studies of Nickel Substituted Polycrystalline Zinc Spinel Ferrites for Structural and Vibrational Investigations
2CreatorAuthor's name, affiliation, country H. A. DAWOUD*, L. ABU OUDA and S. K. K. SHAAT
Department of Physics, Faculty of Science, Islamic University, P.O. Box 108, Gaza, Palestine
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Spinel, Ferrite, Nickel, Zinc, Cation
4DescriptionAbstract FT-IR spectra of Ni1-sZnsFe2O4 spinel ferrite, s changed by 0.2 according to 0.0 ≤ s ≤ 1.0, have been analyzed in the frequency range (350−1000)−1. Six polycrystalline ferrites samples were synthesized using the conventional standard double sintering ceramic method. Two main absorption bands were observed, their positions were found to be strongly dependent on s-value. The high frequency band in the range 550-600 cm−1 and a low frequency band at around 400 cm−1 were assigned to tetrahedral Td and octahedral Oh sites, respectively, of spinel lattice. Force constant (FC) was calculated for Tdand Oh sites and was found to decrease with increasing Zn ions. Threshold frequency νth for the electronic transition was determined and found to increase with increasing Zn ions. Cations distribution for the prepared mixed ferrite was concluded based on the FT-IR spectra. The ionic radii for each site were correlated to the cations distribution of the given ferrite.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  6 , Number  (2), (2017)
12LanuguageEnglish=en en
13RelationSupp.files
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Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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