Indexing Metadata
Preparation, Spectroscopy and X-Ray Structure Analysis of N, Nʹ-Bis(3-nitrophenylmethylene)- cyclohexane-1,2-diamine |
| DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
| 1 | Title | Title of Document | Preparation, Spectroscopy and X-Ray Structure Analysis of N, Nʹ-Bis(3-nitrophenylmethylene)- cyclohexane-1,2-diamine |
| 2 | Creator | Author's name, affiliation, country | KODJO CHARLES GUILLAUME*, KANGAH NIAMEKE JEAN-BAPTISTE, KABLAN AHMONT LANDRY CLAUDE, BOSSON ANTOINE KOUAME, KABLAN RICHMOND JEAN FRANCOIS, ZIAO NAHOSSE and RETAILLEAU PASCAL
Laboratoire de Chimie Bioorganique et de Substances Naturelles, Universite Nangui Abrogoua, UFR-SFA, 02 B.P. 801 Abidjan 02, Cote d`Ivoire
Laboratoire de thermodynamique et physicochimie du milieu, Universite Nangui Abrogoua, Cote d`Ivoire
UFR des Sciences Biologiques, Universite Peleforo Gon Coulibaly de Korhogo, BP 1328 Korhogo, Cote d`Ivoire
Laboratoire de Cristallographie et Physique Moleculaire, UFR SSMT (Sciences des Structure et de la Matiere Technologique), Universite Felix Houphouet Boigny, 01 BP V34 Abidjan 01, Cote d`Ivoire
Institut de Chimie des Substances Naturelles, 1 av. de la Terrasse, 91198, Gif sur Yvette
|
| 3 | Subject | Dicipline(s) | Chemical Science |
| 3 | Subject | Keywords | Schiff base, α-Diimine, Crystal structure, Enantiopure, Hydrogen bonds, I2/a space group |
| 4 | Description | Abstract | The compound N, Nʹ-Bis(3-nitrophenylmethylene)cyclohexane-1,2-diamine (α-diimine Shiff base) was synthesized and characterized by MS, IR, NMR 1H and X-ray single crystal analysis. While the cyclohexane-1,2-diamine used for the synthesis of this composite is a racemic cis and trans mixture, we observed by x-ray diffraction for the product N,Nʹ-bis(3-nitrophenylmethylene) cyclohexane-1,2-diamine only the (1R,2R)trans enantiopure. The crystalline network cohesion of this compound is assured by a combination of C-H...O and C-H...N hydrogen bonds. It crystallizes in the monoclinic non-standard I2/a space group |
| 5 | Publishers | Organizing agency, location | WWW Publications, India |
| 6 | Contributor | Sponsor(s) | - |
| 7 | Date | Date (YYYY-MM-DD) | - |
| 8 | Type | Status & genre | Peer-reviewed Article |
| 8 | Type | Type | |
| 9 | Formate | File Formate | PDF |
| 10 | Identifier | Uniform Resource Identifier | Click Here |
| 10 | Identifier | Digital Object Identifier | |
| 11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 6 , Number (2), (2017) |
| 12 | Lanuguage | English=en | en |
| 13 | Relation | Supp.files | |
| 14 | Coverage | | - |
| 15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
|
