| DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
| 1 | Title | Title of Document | Polymerization of Acrylonitrile Initiated by
Cerium(IV) / p-Aminoacetophenone Redox System
- A Kinetic Study
|
| 2 | Creator | Author's name, affiliation, country | M. PALANIVELU* and A. AFROOS BANU
P.G and Research Department of Chemistry,
Khadir Mohideen College, Adirampattinam ? 614 701, Tamilnadu, India
|
| 3 | Subject | Dicipline(s) | Chemical Science |
| 3 | Subject | Keywords | Acrylonitrile, Ceric ion, p-Aminoacetophenone, Radical polymerization |
| 4 | Description | Abstract | The kinetics of aqueous polymerization of acrylonitrile initiated by the Ce(IV)/p-amino-acetophenone (Ce(IV) ? AAP) redox system in aqueous solution of sulfuric acid medium has been studied under nitrogen atmosphere in the temperature range 30-80 ?C. The rate of polymerization (Rp) and the disappearance of Cerium(IV) have been measured at various concentrations of monomer, initiator, activator and sulfuric acid. The temperature dependence of the rate was studied and the activation parameters were computed using Arrhenius plot. A mechanism consistent with the experimental data is proposed and discussed |
| 5 | Publishers | Organizing agency, location | WWW Publications, India |
| 6 | Contributor | Sponsor(s) | - |
| 7 | Date | Date (YYYY-MM-DD) | - |
| 8 | Type | Status & genre | Peer-reviewed Article |
| 8 | Type | Type | |
| 9 | Formate | File Formate | PDF |
| 10 | Identifier | Uniform Resource Identifier | Click Here |
| 10 | Identifier | Digital Object Identifier | |
| 11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 5 , Number (4), (2016) |
| 12 | Lanuguage | English=en | en |
| 13 | Relation | Supp.files | |
| 14 | Coverage | | - |
| 15 | Copyright | Copyright and permissions | |
