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Kinetics and Mechanism of Oxidation of 4-Oxo-4-phenylbutanoic Acid by N-Bromoanisamide in Aqueous Acetic Acid Medium

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1TitleTitle of DocumentKinetics and Mechanism of Oxidation of 4-Oxo-4-phenylbutanoic Acid by N-Bromoanisamide in Aqueous Acetic Acid Medium
2CreatorAuthor's name, affiliation, country G. A. SEYED DAMEEM*and N. A. MOHAMED FAROOK
PG and Research Department of Chemistry Khadir Mohideen College, Adirampattinam-614701, Tamilnadu, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Kinetics, Oxidation, N-bromoanisamide, 4-Oxoacids, 3-Benzoylpropionic acid
4DescriptionAbstract Kinetics and mechanism of oxidation of 4-oxo-4-phenylbutanoic acid (KA) by N-bromoanisamide (NBAS) in aqueous acetic acid medium have been studied potentiometrically. The reactions exhibit a first order rate dependence each with respect to oxidant, substrate and [H+]. The reaction rate retarded by the addition of anisamide. The decrease in dielectric constant of the medium increases rate of the reaction. Increase in ionic strength, by the addition of sodium perchlorate has no effect on the rate constant. The effect of temperature on the reaction has been investigated in the temperature range 308-323 K. Based on the kinetic results and the product analysis, a suitable mechanism has been proposed for the reaction of NBAS with 4-oxo-4- phenylbutanoic acid
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier DOI:10.7598/cst2016.1351
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  5 , Number  (4), (2016)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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