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Studies of Fe(II), Mn(II), Cr(II), Ni(II), Co(II) and Cu(II) Complexes with Schiff Base Derived from 2-Amino-4,6-dimethylbenzothiazole and Pyridine-2-aldehyde

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1TitleTitle of DocumentStudies of Fe(II), Mn(II), Cr(II), Ni(II), Co(II) and Cu(II) Complexes with Schiff Base Derived from 2-Amino-4,6-dimethylbenzothiazole and Pyridine-2-aldehyde
2CreatorAuthor's name, affiliation, country V.G. DESHPANDE and SEEMA I HABIB*
Department of Chemistry, G. M. Momin Women?s College, Bhiwandi, Maharashtra, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Substituted benzothiazole Schiff bases, Transition metal complexes, Spectral analysis, Antimicrobial activity
4DescriptionAbstract As it is proved that the transition metal complexes have drug activities, hence we have synthesized heterocyclic Schiff bases. Six complexes of Co(II), Ni(II), Fe(III), Mn(II), Cr(II) and Cu(II) Schiff bases have been prepared. All ligands and its metal complexes the structures of the complexes have been proposed by analytical data, conductivity measurement, magnetic moment, IR, 1H NMR spectra and thermal studies. Analytical data confirmed 1:2 (metal:ligand) stoichiometry and the spectral data suggest that all Fe(III), Mn(II), Cr(II), Ni(II) and Co(II) complexes have octahedral geometry where as the Cu(II) metal complex shows the square planar geometry. The molar conductance values of metal complexes suggest their non electrolytic nature. The IR spectral data reveals that the ligand behaves as bidentate with ON donor atoms sequence towards central metal ion. Antibacterial and antifungal activities of ligands and its metal complexes were performed in vitro against E.coli, S. typhi, S. aureus, B. subtilis and against various fungi like P.chrysogenum, A. niger, F. moniliformae and A.Flavus. The complexes show more activity compare to the ligand.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  6 , Number  (3), (2017)
12LanuguageEnglish=en en
13RelationSupp.files
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Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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