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Electrochemical Behaviour and Adsorptive Stripping Voltammetric Determination of Cyclophosphamide

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1TitleTitle of DocumentElectrochemical Behaviour and Adsorptive Stripping Voltammetric Determination of Cyclophosphamide
2CreatorAuthor's name, affiliation, country PRIYANKA SINHA, SACHIN DOI and D. K. SHARMA*
Electrochemical Sensor Research Laboratory, Department of Chemistry, University of Rajasthan, Jaipur (Rajasthan)-302004, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Cyclophosphamide, Cyclic voltammetry, Differential pulse cathodic adsorptive stripping voltammetry, Diffusion controlled, LOD and LOQ
4DescriptionAbstract Electrochemical behaviour of anticancer medication cyclophosphamide was studied in BR buffer of pH 3.0 at glassy carbon electrode using cyclic voltammetry. Cyclophosphamide gave one well defined irreversible reduction peak at potential -1.4V v/s Ag/AgCl reference electrode. The reduction was diffusion controlled and all kinetic parameters were calculated and a reduction mechanism was proposed based on the observed experimental data. Furthermore, differential pulse cathodic adsorptive stripping voltammetry (DPCAdSV) was optimized for determination of cyclophosphamide in bulk form and human urine as biological sample. Good linearity range and obtained LOD and LOQ of 1.1?10-6 M and 3.67?10-6 M respectively indicated about the good sensitivity of developed method.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  7 , Number  (2), (2018)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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