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Synthesis and Crystal Structure of a Triply-Bridged Binuclear Cobalt(II) Dichloroacetate

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1TitleTitle of DocumentSynthesis and Crystal Structure of a Triply-Bridged Binuclear Cobalt(II) Dichloroacetate
2CreatorAuthor's name, affiliation, country M. GOGOI, S.J. BHARALI and B. K. DAS*
Department of Chemistry, Gauhati University, Guwahati-781014, Assam, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Cobalt(II) dichloroacetate, Aqua-bridged complex, Crystal structure
4DescriptionAbstract A triply-bridged cobalt(II) tetracarboxylate complex, [Co2(η-OH2)(η-CHCl2COO)21-CHCl2COO)2(py)4] has been prepared and its crystal structure has been determined by single crystal x-ray diffraction to find that in this dinuclear cobalt(II) complex, the two metal centres are bridged by a water molecule and two dichloroacetato ligands. Each Co(II) centre is further coordinated to one monodentate dichloroacetato and two pyridine ligands. Supramolecular interactions stabilize the complex in the solid state.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  7 , Number  (1), (2018)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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