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Synthesis and Pyrolytic Studies of Schiff Base Derivatives of Heterotrinucleic[AlIII-SnII-BIII]-µ-oxoisopropoxide |
| DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
| 1 | Title | Title of Document | Synthesis and Pyrolytic Studies of Schiff Base Derivatives of Heterotrinucleic[AlIII-SnII-BIII]-µ-oxoisopropoxide |
| 2 | Creator | Author's name, affiliation, country | RAJESH KUMAR
Department of Chemistry, Haryana Institute of Engineering & Technology,
Kaithal-136027, Haryana, India |
| 3 | Subject | Dicipline(s) | Chemical Science |
| 3 | Subject | Keywords | Heteronucleic-µ-oxoalkoxides, Aluminium, Tin, Boron, Schiff bases, TG analysis |
| 4 | Description | Abstract | New Schiff base derivatives of heteronucleic-µ-oxoisopropoxide[SnO2AlB(Opri)4] have been synthesized by thermal condensation of µ-oxoisopropoxide with salicylidene-aniline (HSB1), salicylidene-o-toluidene (HSB2), salicylidene-p-toluidene (HSB3) and salicylidene-p-chloroaniline (HSB4) in different molar ratios (1:1-1:2) yielded the compounds of the type [SnO2AlB(Opri)4-n (SB)n] (where n is 1-2 and SB = Schiff base anion). The Schiff base derivatives have been characterized by elemental, spectral (IR, 1H, 13C, 27Al, 119Sn and 11B NMR), thermal and molecular weight measurement. Hydrothermally assisted sol-gel process gives the hydrolyzed product and thermal study of these products favors the formation of multi-component oxides. The studies reveal that Schiff base derivatives are polymeric in nature and low susceptible to hydrolysis as compared to parent compound and may prove excellent precursors for the mixed metal oxides. |
| 5 | Publishers | Organizing agency, location | WWW Publications, India |
| 6 | Contributor | Sponsor(s) | - |
| 7 | Date | Date (YYYY-MM-DD) | - |
| 8 | Type | Status & genre | Peer-reviewed Article |
| 8 | Type | Type | |
| 9 | Formate | File Formate | PDF |
| 10 | Identifier | Uniform Resource Identifier | Click Here |
| 10 | Identifier | Digital Object Identifier | |
| 11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 1 , Number (2), (2012) |
| 12 | Lanuguage | English=en | en |
| 13 | Relation | Supp.files | |
| 14 | Coverage | | - |
| 15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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