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Crystal and Molecular Structure Study of the Complex Cd(L) 2Br2.C2H5OH (L=2-(4-Methylsulfanyl phenyl)-1H-benzimidazole) |
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1 | Title | Title of Document | Crystal and Molecular Structure Study of the Complex Cd(L) 2Br2.C2H5OH (L=2-(4-Methylsulfanyl phenyl)-1H-benzimidazole) |
2 | Creator | Author's name, affiliation, country | M.N. MANJUNATHA1, MOHAMED ZIAULLA2* and M. CHANDRAKALA3 1Department of Chemistry, M.S. Ramaiah Institute of Technology, M.S.R Nagar,
Bangalore-560 054, Karnataka, India
2Department of Chemistry, Impact College of Engineering and Applied Sciences, Bangalore-560 092, Karnataka, India
3Department of Chemistry, Bangalore Institute of Technology,
Bangalore-560 004, Karnataka, India
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3 | Subject | Dicipline(s) | Chemical Science |
3 | Subject | Keywords | Benzimidazole derivative, Metal ligand complex, Crystal structure, Weak interactions |
4 | Description | Abstract | The complex, Cd(L)2Br2.C2H5OH, contains an ethanol molecule and dibromocadmate(II) coordinated to two benzimidazole moiety. In the crystal structure, the ethanol molecule is involved in four hydrogen bonds, viz. N-H...O, C-H...O, C-H...Br and O-H...Br intermolecular interactions network. Further the supramolecular assembly is stabilized by π-π stacking interactions between the benzimidazole and thiomethyl phenyl rings. Additionally, the metal ion, Cd(II) exhibits a distorted tetrahedral coordination of the bromine atoms. |
5 | Publishers | Organizing agency, location | WWW Publications, India |
6 | Contributor | Sponsor(s) | - |
7 | Date | Date (YYYY-MM-DD) | - |
8 | Type | Status & genre | Peer-reviewed Article |
8 | Type | Type | |
9 | Formate | File Formate | PDF |
10 | Identifier | Uniform Resource Identifier | Click Here |
10 | Identifier | Digital Object Identifier | |
11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 7 , Number (1), (2018) |
12 | Lanuguage | English=en | en |
13 | Relation | Supp.files | |
14 | Coverage | | - |
15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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