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Crystal and Molecular Structure Study of the Complex Cd(L) 2Br2.C2H5OH (L=2-(4-Methylsulfanyl phenyl)-1H-benzimidazole)

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1TitleTitle of DocumentCrystal and Molecular Structure Study of the Complex Cd(L) 2Br2.C2H5OH (L=2-(4-Methylsulfanyl phenyl)-1H-benzimidazole)
2CreatorAuthor's name, affiliation, country M.N. MANJUNATHA1, MOHAMED ZIAULLA2* and M. CHANDRAKALA3
1Department of Chemistry, M.S. Ramaiah Institute of Technology, M.S.R Nagar, Bangalore-560 054, Karnataka, India
2Department of Chemistry, Impact College of Engineering and Applied Sciences, Bangalore-560 092, Karnataka, India
3Department of Chemistry, Bangalore Institute of Technology, Bangalore-560 004, Karnataka, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Benzimidazole derivative, Metal ligand complex, Crystal structure, Weak interactions
4DescriptionAbstract The complex, Cd(L)2Br2.C2H5OH, contains an ethanol molecule and dibromocadmate(II) coordinated to two benzimidazole moiety. In the crystal structure, the ethanol molecule is involved in four hydrogen bonds, viz. N-H...O, C-H...O, C-H...Br and O-H...Br intermolecular interactions network. Further the supramolecular assembly is stabilized by π-π stacking interactions between the benzimidazole and thiomethyl phenyl rings. Additionally, the metal ion, Cd(II) exhibits a distorted tetrahedral coordination of the bromine atoms.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  7 , Number  (1), (2018)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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