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Synthesis and Characterisation of Oxovanadium(V) Derivatives of O,O`-Bis(α-naphthyl, β-naphthyl and 2, 3, 5-trimethylphenyl)dithiophosphates

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1TitleTitle of DocumentSynthesis and Characterisation of Oxovanadium(V) Derivatives of O,O`-Bis(α-naphthyl, β-naphthyl and 2, 3, 5-trimethylphenyl)dithiophosphates
2CreatorAuthor's name, affiliation, country SATINDER K. JUNEJA1, MUKHTYAR S. SAINI2, JAYA DWIVEDI3 and ARAN KUMAR*2
1Department of Chemistry, Govt. College for Women Parade, Jammu, J and K, 180001, India
2Department of Chemistry, Govt. G. M. Science College, Jammu, J and K- 180001, India
3Department of Chemistry, Banasthali University, Jaipur, Rajasthan- 304022, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords α-Naphthyl, β-Naphthyl, 2,3,5-Trimethylphenyl, Dithiophosphates, Vanadium dithiophosphates, Vanadiumoxytrichloride
4DescriptionAbstract Reactions of VOCl3 with sodium salts of O,O`-bis(α-naphthyl, β-naphthyl or 2,3,5-trimethylphenyl) dithiophosphate ligands, [{α-C10H7O-, β-C10H7O-, or (CH3)3C6H2O}2PS2Na], in 1:3 molar ratio in toluene yielded new seven coordinated vanadium derivatives of the type [{(RO) 2PS2}3VO] (where R = α-C10H7O-, β-C10H7O- and (CH3) 3C6H2O-). The reactions of [OGOVOCl] (where G = -CH2CH2- or -CH2CH2CH2-), with sodium salts of O,O-bis(α-naphthyl, β-naphthyl or 2,3,5-trimethylphenyl) dithiophosphate ligands, [{α-C10H7O-, β-C10H7O- and (CH3) 3C6H2O}2PS2Na}, in 1:1 molar ratio in toluene were quite facile which afforded 5-coordinated soluble complexes corresponded to formula [OGOVOS2P(OR) 2]. These compounds have been characterized by elemental analysis (C, H, V and S), mass, IR and NMR (1H, 13C and 31P) spectroscopic studies which indicates bidentate linkages of dithiophosphate moieties leading to pentagonal bipyramidal and square pyramidal geometry around the vanadium(V) atom.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier DOI:10.7598/cst2018.1472
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  7 , Number  (2), (2018)
12LanuguageEnglish=en en
13RelationSupp.files
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Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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