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Synthesis and Characterisation of Oxovanadium(V) Derivatives of O,O`-Bis(α-naphthyl, β-naphthyl and 2, 3, 5-trimethylphenyl)dithiophosphates |
| DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
| 1 | Title | Title of Document | Synthesis and Characterisation of Oxovanadium(V) Derivatives of O,O`-Bis(α-naphthyl, β-naphthyl and 2, 3, 5-trimethylphenyl)dithiophosphates |
| 2 | Creator | Author's name, affiliation, country | SATINDER K. JUNEJA1, MUKHTYAR S. SAINI2, JAYA DWIVEDI3 and ARAN KUMAR*2
1Department of Chemistry, Govt. College for Women Parade,
Jammu, J and K, 180001, India
2Department of Chemistry, Govt. G. M. Science College, Jammu, J and K- 180001, India
3Department of Chemistry, Banasthali University, Jaipur, Rajasthan- 304022, India
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| 3 | Subject | Dicipline(s) | Chemical Science |
| 3 | Subject | Keywords | α-Naphthyl, β-Naphthyl, 2,3,5-Trimethylphenyl, Dithiophosphates, Vanadium dithiophosphates, Vanadiumoxytrichloride |
| 4 | Description | Abstract | Reactions of VOCl3 with sodium salts of O,O`-bis(α-naphthyl, β-naphthyl or 2,3,5-trimethylphenyl) dithiophosphate ligands, [{α-C10H7O-, β-C10H7O-, or (CH3)3C6H2O}2PS2Na], in 1:3 molar ratio in toluene yielded new seven coordinated vanadium derivatives of the type [{(RO) 2PS2}3VO] (where R = α-C10H7O-, β-C10H7O- and (CH3) 3C6H2O-). The reactions of
[OGOVOCl] (where G = -CH2CH2- or -CH2CH2CH2-), with sodium salts of O,O-bis(α-naphthyl, β-naphthyl or 2,3,5-trimethylphenyl) dithiophosphate ligands, [{α-C10H7O-, β-C10H7O- and (CH3) 3C6H2O}2PS2Na}, in 1:1 molar ratio in toluene were quite facile which afforded 5-coordinated
soluble complexes corresponded to formula [OGOVOS2P(OR) 2]. These compounds have been characterized by elemental analysis (C, H, V and S), mass, IR and NMR (1H, 13C and 31P) spectroscopic studies which indicates bidentate linkages of dithiophosphate moieties leading to pentagonal bipyramidal and square pyramidal geometry around the vanadium(V) atom.
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| 5 | Publishers | Organizing agency, location | WWW Publications, India |
| 6 | Contributor | Sponsor(s) | - |
| 7 | Date | Date (YYYY-MM-DD) | - |
| 8 | Type | Status & genre | Peer-reviewed Article |
| 8 | Type | Type | |
| 9 | Formate | File Formate | PDF |
| 10 | Identifier | Uniform Resource Identifier | Click Here |
| 10 | Identifier | Digital Object Identifier | |
| 11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 7 , Number (2), (2018) |
| 12 | Lanuguage | English=en | en |
| 13 | Relation | Supp.files | |
| 14 | Coverage | | - |
| 15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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