Indexing Metadata
Synthesis, Characterization, Thermal and
Non-Isothermal Degradation Studies of Two Mononuclear Nickel and Copper Complexes Containing Schiff Base Moiety
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| DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
| 1 | Title | Title of Document | Synthesis, Characterization, Thermal and
Non-Isothermal Degradation Studies of Two Mononuclear Nickel and Copper Complexes Containing Schiff Base Moiety
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| 2 | Creator | Author's name, affiliation, country | ANJALI TIWARI*, A. P. MISHRA and BRAJENDRA S. KUSMARIYA
Department of Chemistry, Dr. H.S. Gour Central University, Sagar, 470003, India |
| 3 | Subject | Dicipline(s) | Chemical Science |
| 3 | Subject | Keywords | Schiff base, Nickel and Copper complexes, Thermal analysis, Non-isothermal kinetics, Coats-Redfern methods |
| 4 | Description | Abstract | Herein we report two mononuclear nickel and Copper complexes of a tridentate 2, 4-dichloro-6-{[(5-chloro-2-hydroxyphenyl)imino]methyl}phenol ligand (dcp) derived from 3,5-dichlorosalicylaldehyde and 2-amino-4-chlorophenol [general formula: ML.xH2O {L= dcp; M = NiII and CuII }]. The synthesized compounds have been characterized by elemental; FT-IR, UV-Vis, molar conductance and thermal analysis studies. TGA analysis was performed to determine the thermal stability of synthesized compounds under nitrogen atmosphere up to 800 ?C K at 10 ?C min-1 heating rate. Thermal studies show the degradation pattern of complexes. Non-isothermal kinetic parameters, such as activation energy (E*), entropy of activation (ΔS*), enthalpy of activation (ΔH*), frequency factor (Z) and free energy change (ΔG) have been calculated using Coats-Redfern (C-R), Piloyan-Novikova (P-N) and Horowitz-Metzger (H-M) methods. |
| 5 | Publishers | Organizing agency, location | WWW Publications, India |
| 6 | Contributor | Sponsor(s) | - |
| 7 | Date | Date (YYYY-MM-DD) | - |
| 8 | Type | Status & genre | Peer-reviewed Article |
| 8 | Type | Type | |
| 9 | Formate | File Formate | PDF |
| 10 | Identifier | Uniform Resource Identifier | Click Here |
| 10 | Identifier | Digital Object Identifier | |
| 11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 8 , Number (1), (2019) |
| 12 | Lanuguage | English=en | en |
| 13 | Relation | Supp.files | |
| 14 | Coverage | | - |
| 15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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