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Structural Studies of Sm/Zr Substituted Mg-Mn Ferrites

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1TitleTitle of DocumentStructural Studies of Sm/Zr Substituted Mg-Mn Ferrites
2CreatorAuthor's name, affiliation, country G.BHANU PRAVEEN* and A. D. P.RAO
Department of Nuclear Physics, Andhra University, Visakhapatnam 530003, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Lattice parameter, Particle size, Cation distribution, Bond length, Structure
4DescriptionAbstract Two series of Sm/Zr substituted Mg-Mn ferrite materials have been developed having the chemical compositions Mg0.95Mn0.05Sm2xFe2-2xO4 and Mg0.95Mn0.05+xZrxFe2-2xO4. These materials nanoparticles size ferrites are prepared by using sol-gel method while following ceramic method bulk (larger particle size) ferries are prepared. The value of x varies from 0.0 to 0.5. These are characterized with density, XRD, EDAX, SEM and TEM studies. Based on the obtained results cation distribution is proposed. Samarium is found to occupy B sites while zirconium occupied A and B sites replacing Fe3+ ions. Density of all the materials found to increase except at higher values of Sm concentration. Lattice parameter of Sm substituted ferrites is found to increase with the rise of Sm content while it decreases with the rise of Zr content. These values obtained due to XRD studies have fair agreement with the theoretically computed lattice parameter values based on the proposed cation distribution. Obtained particle size values due to XRD, SEM and TEM are compared, which are in the nano range.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  8 , Number  (2), (2019)
12LanuguageEnglish=en en
13RelationSupp.files
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Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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