Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
Home | Table of Contents | Submit an article | Subscribe | Login | Register

Indexing Metadata

New Insights into the Chemistry of cis-Dioxomolybdenum(VI) Schiff Base Complexes with Macrocyclic Ligands

DUBLINCOREMETADATA ITEM METADATA FOR THIS DOCUMENT
1TitleTitle of DocumentNew Insights into the Chemistry of cis-Dioxomolybdenum(VI) Schiff Base Complexes with Macrocyclic Ligands
2CreatorAuthor's name, affiliation, country RAMESH KUMAR GAUTAM1*, CHANDRA PRAKASH SINGH2, DINESH KUMAR3 and DEVENDRA PRATAP RAO1
1Department of Chemistry, D.A.V. (P.G.) College, Kanpur-208001, U.P., India
2Department of Chemistry, D.B.S. (P.G.) College, Kanpur-208006, U.P., India
3Department of Chemistry, Bipin Bihari College, Jhansi, U.P., India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Dioxomolybdenum(VI), Thenil, β-Diketones, Macrocyclic complexes, Schiff base
4DescriptionAbstract Preparation of one parent dioxomolybdenum(VI) complex of formula [MoO2(L)](acac)2 with a Schiff base, obtained from condensation of thenil with 2,3-diamino-5-chloropyridine and four new complexes having formula [MoO2 (ML)](acac) 2, derived from cyclization of [MoO2 (L)](acac) 2 with β-diketones are reported in this research paper. The prepared five dioxomolybdenum(VI) complexes have been described by elemental analyses, molar conductance, UV-Vis, IR, NMR and thermal studies. The feasibility of coordination number of molybdenum metal is six. All five complexes of dioxomolybdenum(VI) have octahedral geometry. The octahedral coordination circle of molybdenum in synthesized dioxomolybdenum complexes is completed by two oxo oxygen atoms and four nitrogen atoms from derived ligand. The shape of synthesized dioxomolybdenum(VI) complexes have distorted octahedral. All the synthesized complexes showed moderate activity against S. aureus and S. typhi, the improvement in the antibacterial activity being explained on the basis of chelation hypothesis.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier DOI:10.7598/cst2019.1594
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  8 , Number  (4), (2019)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
Home | Table of Contents | Submit an article | Subscribe | Login | Register