Indexing Metadata
New Insights into the Chemistry of
cis-Dioxomolybdenum(VI) Schiff Base Complexes with Macrocyclic Ligands
|
DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
1 | Title | Title of Document | New Insights into the Chemistry of
cis-Dioxomolybdenum(VI) Schiff Base Complexes with Macrocyclic Ligands
|
2 | Creator | Author's name, affiliation, country | RAMESH KUMAR GAUTAM1*, CHANDRA PRAKASH SINGH2, DINESH KUMAR3 and DEVENDRA PRATAP RAO1 1Department of Chemistry, D.A.V. (P.G.) College, Kanpur-208001, U.P., India
2Department of Chemistry, D.B.S. (P.G.) College, Kanpur-208006, U.P., India
3Department of Chemistry, Bipin Bihari College, Jhansi, U.P., India
|
3 | Subject | Dicipline(s) | Chemical Science |
3 | Subject | Keywords | Dioxomolybdenum(VI), Thenil, β-Diketones, Macrocyclic complexes, Schiff base |
4 | Description | Abstract | Preparation of one parent dioxomolybdenum(VI) complex of formula [MoO2(L)](acac)2 with a Schiff base, obtained from condensation of thenil with 2,3-diamino-5-chloropyridine and four new complexes having formula [MoO2 (ML)](acac) 2, derived from cyclization of [MoO2 (L)](acac) 2 with β-diketones are reported in this research paper. The prepared five dioxomolybdenum(VI) complexes have been described by elemental analyses, molar conductance, UV-Vis, IR, NMR and thermal studies. The feasibility of coordination number of molybdenum metal is six. All five complexes of dioxomolybdenum(VI) have octahedral geometry. The octahedral coordination circle of molybdenum in synthesized dioxomolybdenum complexes is completed by two oxo oxygen atoms and four nitrogen atoms from derived ligand. The shape of synthesized dioxomolybdenum(VI) complexes have distorted octahedral. All the synthesized complexes showed moderate activity against S. aureus and S. typhi, the improvement in the antibacterial activity being explained on the basis of chelation hypothesis. |
5 | Publishers | Organizing agency, location | WWW Publications, India |
6 | Contributor | Sponsor(s) | - |
7 | Date | Date (YYYY-MM-DD) | - |
8 | Type | Status & genre | Peer-reviewed Article |
8 | Type | Type | |
9 | Formate | File Formate | PDF |
10 | Identifier | Uniform Resource Identifier | Click Here |
10 | Identifier | Digital Object Identifier | |
11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 8 , Number (4), (2019) |
12 | Lanuguage | English=en | en |
13 | Relation | Supp.files | |
14 | Coverage | | - |
15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
|