DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
1 | Title | Title of Document | Spectrophotometric Study of Complexation Between Some Salen Type Schiff Bases and Dimethyltin(IV) Dichloride |
2 | Creator | Author's name, affiliation, country | ALI HOSSEIN KIANFAR and ISLAM ABROSHAN Department of Chemistry, Isfahan University of Technology, Isfahan, 84156-83111, Iran
Department of Chemistry, Yasouj University, Yasouj, Iran |
3 | Subject | Dicipline(s) | Chemical Science |
3 | Subject | Keywords | Schiff base, Dimethyltin dichloride, Formation constant, Complex formation |
4 | Description | Abstract | UV-Vis spectrophotometric study of the complex formation of Salen type Schiff bases as donors with Me2SnCl2 as an acceptor have been investigated in chloroform. The formation constants were measured using UV-Vis spectrophotometric titration for 1:1 complex formation and by Ketelaar equation in the range 15-30 oC. Thermodynamic parameters were determined by using Von’t Hoff equation. The formation constant of the Schiff bases with dimethyletin(IV) dichloride in chloroform decreases according to the following trend: 3- MeOSalen > 4- MeOSalen > 5- MeOSalen » Salen > 5- BrSalen and Me2Salen > Salbn » Salpn > Salen > Salophen |
5 | Publishers | Organizing agency, location | WWW Publications, India |
6 | Contributor | Sponsor(s) | - |
7 | Date | Date (YYYY-MM-DD) | - |
8 | Type | Status & genre | Peer-reviewed Article |
8 | Type | Type | |
9 | Formate | File Formate | PDF |
10 | Identifier | Uniform Resource Identifier | Click Here |
10 | Identifier | Digital Object Identifier | |
11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 2 , Number (S1), (2013) |
12 | Lanuguage | English=en | en |
13 | Relation | Supp.files | |
14 | Coverage | | - |
15 | Copyright | Copyright and permissions | |